Goethite, data from Jennifer Kelly , analyzed by Perkin Elmer FTIR Spectrometer. KBr disk, KBr has been subtracted 4400, 51.77 4398, 51.71 4396, 51.78 4394, 51.84 4392, 51.79 4390, 51.74 4388, 51.81 4386, 51.87 4384, 51.81 4382, 51.82 4380, 51.89 4378, 51.93 4376, 51.9 4374, 51.89 4372, 51.92 4370, 51.93 4368, 51.94 4366, 51.98 4364, 52.09 4362, 52.15 4360, 52.19 4358, 52.24 4356, 52.18 4354, 52.14 4352, 52.25 4350, 52.29 4348, 52.31 4346, 52.38 4344, 52.39 4342, 52.42 4340, 52.41 4338, 52.3 4336, 52.29 4334, 52.4 4332, 52.43 4330, 52.39 4328, 52.37 4326, 52.35 4324, 52.35 4322, 52.42 4320, 52.48 4318, 52.58 4316, 52.53 4314, 52.44 4312, 52.5 4310, 52.55 4308, 52.48 4306, 52.5 4304, 52.67 4302, 52.79 4300, 52.84 4298, 52.82 4296, 52.75 4294, 52.68 4292, 52.74 4290, 52.86 4288, 52.88 4286, 52.84 4284, 52.84 4282, 52.86 4280, 52.85 4278, 52.88 4276, 52.88 4274, 52.83 4272, 52.88 4270, 52.96 4268, 52.96 4266, 52.98 4264, 53.03 4262, 53.19 4260, 53.24 4258, 53.21 4256, 53.21 4254, 53.15 4252, 53.15 4250, 53.13 4248, 53.1 4246, 53.18 4244, 53.31 4242, 53.42 4240, 53.42 4238, 53.36 4236, 53.29 4234, 53.27 4232, 53.37 4230, 53.43 4228, 53.34 4226, 53.39 4224, 53.57 4222, 53.53 4220, 53.41 4218, 53.36 4216, 53.42 4214, 53.57 4212, 53.58 4210, 53.49 4208, 53.49 4206, 53.58 4204, 53.74 4202, 53.82 4200, 53.71 4198, 53.73 4196, 53.74 4194, 53.68 4192, 53.75 4190, 53.84 4188, 53.86 4186, 53.89 4184, 53.94 4182, 53.95 4180, 53.9 4178, 53.87 4176, 53.87 4174, 53.9 4172, 53.96 4170, 54.1 4168, 54.15 4166, 54.13 4164, 54.1 4162, 54.08 4160, 54.07 4158, 54.09 4156, 54.21 4154, 54.28 4152, 54.18 4150, 54.26 4148, 54.37 4146, 54.32 4144, 54.32 4142, 54.35 4140, 54.38 4138, 54.4 4136, 54.41 4134, 54.43 4132, 54.48 4130, 54.5 4128, 54.5 4126, 54.55 4124, 54.62 4122, 54.6 4120, 54.6 4118, 54.65 4116, 54.66 4114, 54.67 4112, 54.64 4110, 54.62 4108, 54.64 4106, 54.59 4104, 54.54 4102, 54.62 4100, 54.71 4098, 54.78 4096, 54.72 4094, 54.72 4092, 54.85 4090, 54.98 4088, 54.97 4086, 54.91 4084, 55.02 4082, 55.05 4080, 55 4078, 55.03 4076, 55.09 4074, 55.07 4072, 55.09 4070, 55.18 4068, 55.22 4066, 55.18 4064, 55.18 4062, 55.17 4060, 55.13 4058, 55.16 4056, 55.26 4054, 55.33 4052, 55.33 4050, 55.36 4048, 55.38 4046, 55.33 4044, 55.35 4042, 55.37 4040, 55.41 4038, 55.47 4036, 55.44 4034, 55.38 4032, 55.42 4030, 55.5 4028, 55.52 4026, 55.5 4024, 55.57 4022, 55.61 4020, 55.55 4018, 55.52 4016, 55.58 4014, 55.64 4012, 55.69 4010, 55.74 4008, 55.75 4006, 55.79 4004, 55.87 4002, 55.91 4000, 55.91 3998, 55.95 3996, 56 3994, 55.95 3992, 55.94 3990, 56.02 3988, 56.07 3986, 56.07 3984, 56.06 3982, 56.11 3980, 56.15 3978, 56.22 3976, 56.31 3974, 56.27 3972, 56.21 3970, 56.17 3968, 56.15 3966, 56.25 3964, 56.42 3962, 56.43 3960, 56.42 3958, 56.46 3956, 56.43 3954, 56.47 3952, 56.56 3950, 56.6 3948, 56.59 3946, 56.65 3944, 56.74 3942, 56.68 3940, 56.61 3938, 56.6 3936, 56.79 3934, 57.02 3932, 57.01 3930, 56.92 3928, 56.94 3926, 57.03 3924, 57.02 3922, 57.1 3920, 57.24 3918, 57.25 3916, 57.05 3914, 56.95 3912, 56.99 3910, 57.12 3908, 57.53 3906, 58.02 3904, 57.96 3902, 57.76 3900, 57.55 3898, 57.17 3896, 57.17 3894, 57.67 3892, 57.87 3890, 57.57 3888, 57.81 3886, 57.86 3884, 57.69 3882, 57.89 3880, 57.71 3878, 57.55 3876, 57.93 3874, 58.14 3872, 58.45 3870, 58.27 3868, 57.92 3866, 58.19 3864, 58.23 3862, 58.04 3860, 58.04 3858, 58.67 3856, 59.86 3854, 59.81 3852, 58.27 3850, 57.74 3848, 57.95 3846, 58.39 3844, 58.65 3842, 58.87 3840, 59.12 3838, 59 3836, 58.66 3834, 58.58 3832, 58.49 3830, 58.42 3828, 58.64 3826, 58.76 3824, 59.32 3822, 59.63 3820, 59 3818, 59.08 3816, 58.94 3814, 58.57 3812, 58.72 3810, 59.22 3808, 59.52 3806, 59.26 3804, 59.64 3802, 59.74 3800, 59.2 3798, 59.19 3796, 59.11 3794, 58.95 3792, 59.03 3790, 59.12 3788, 59.23 3786, 59.31 3784, 59.29 3782, 59.52 3780, 59.66 3778, 59.43 3776, 59.33 3774, 59.63 3772, 60.02 3770, 59.98 3768, 59.8 3766, 59.79 3764, 59.71 3762, 60.05 3760, 60.35 3758, 60.18 3756, 60.2 3754, 60.96 3752, 61.48 3750, 60.89 3748, 60.75 3746, 61.37 3744, 60.64 3742, 60.04 3740, 60.54 3738, 61.3 3736, 61.38 3734, 60.83 3732, 60.31 3730, 60.26 3728, 60.64 3726, 60.79 3724, 60.76 3722, 60.7 3720, 60.69 3718, 60.68 3716, 60.93 3714, 61.56 3712, 61.62 3710, 60.95 3708, 60.49 3706, 60.6 3704, 60.9 3702, 60.74 3700, 60.32 3698, 60.31 3696, 60.45 3694, 60.79 3692, 61.43 3690, 61.6 3688, 60.91 3686, 60.63 3684, 60.97 3682, 61.36 3680, 61.84 3678, 62.74 3676, 62.78 3674, 62.04 3672, 62.3 3670, 62.15 3668, 61.55 3666, 61.56 3664, 61.81 3662, 61.89 3660, 62.07 3658, 62.48 3656, 62.31 3654, 62.3 3652, 63.14 3650, 63.34 3648, 62.47 3646, 61.75 3644, 61.71 3642, 61.92 3640, 62.03 3638, 62.08 3636, 62.12 3634, 62.13 3632, 62.64 3630, 63.06 3628, 61.98 3626, 61.16 3624, 61.11 3622, 61.41 3620, 61.51 3618, 61.15 3616, 61.09 3614, 61.21 3612, 61.19 3610, 61.18 3608, 60.81 3606, 60.38 3604, 60.27 3602, 60.28 3600, 60.11 3598, 60.02 3596, 59.92 3594, 59.61 3592, 59.46 3590, 59.69 3588, 59.54 3586, 58.83 3584, 58.4 3582, 58.33 3580, 58.28 3578, 58.18 3576, 58.03 3574, 57.82 3572, 57.75 3570, 57.93 3568, 57.79 3566, 57.15 3564, 56.74 3562, 56.6 3560, 56.47 3558, 56.29 3556, 56.14 3554, 56.09 3552, 55.86 3550, 55.69 3548, 55.65 3546, 55.46 3544, 55.14 3542, 54.86 3540, 54.7 3538, 54.64 3536, 54.49 3534, 54.29 3532, 54.18 3530, 54.11 3528, 53.89 3526, 53.71 3524, 53.53 3522, 53.27 3520, 53.11 3518, 52.97 3516, 52.8 3514, 52.67 3512, 52.63 3510, 52.48 3508, 52.23 3506, 52.11 3504, 51.97 3502, 51.74 3500, 51.58 3498, 51.48 3496, 51.26 3494, 51.04 3492, 50.93 3490, 50.81 3488, 50.63 3486, 50.43 3484, 50.27 3482, 50.11 3480, 49.89 3478, 49.74 3476, 49.6 3474, 49.46 3472, 49.32 3470, 49.13 3468, 48.98 3466, 48.88 3464, 48.79 3462, 48.66 3460, 48.49 3458, 48.36 3456, 48.23 3454, 48.06 3452, 47.91 3450, 47.91 3448, 47.91 3446, 47.72 3444, 47.58 3442, 47.47 3440, 47.32 3438, 47.26 3436, 47.17 3434, 47.05 3432, 47 3430, 46.91 3428, 46.8 3426, 46.73 3424, 46.67 3422, 46.62 3420, 46.6 3418, 46.5 3416, 46.39 3414, 46.36 3412, 46.38 3410, 46.38 3408, 46.34 3406, 46.3 3404, 46.23 3402, 46.13 3400, 46.1 3398, 46.1 3396, 46.06 3394, 46 3392, 45.95 3390, 45.92 3388, 45.9 3386, 45.88 3384, 45.87 3382, 45.88 3380, 45.9 3378, 45.87 3376, 45.85 3374, 45.88 3372, 45.89 3370, 45.83 3368, 45.79 3366, 45.87 3364, 45.98 3362, 46.03 3360, 46.05 3358, 46.11 3356, 46.12 3354, 46.06 3352, 46.03 3350, 46.04 3348, 46.02 3346, 46 3344, 46.07 3342, 46.06 3340, 46 3338, 45.99 3336, 45.99 3334, 46.01 3332, 46.02 3330, 46 3328, 46.01 3326, 46 3324, 45.97 3322, 45.97 3320, 45.97 3318, 45.98 3316, 45.94 3314, 45.97 3312, 45.99 3310, 45.96 3308, 45.92 3306, 45.84 3304, 45.77 3302, 45.78 3300, 45.83 3298, 45.79 3296, 45.73 3294, 45.65 3292, 45.59 3290, 45.63 3288, 45.62 3286, 45.53 3284, 45.43 3282, 45.39 3280, 45.36 3278, 45.3 3276, 45.23 3274, 45.17 3272, 45.11 3270, 45.04 3268, 44.99 3266, 44.96 3264, 44.92 3262, 44.85 3260, 44.76 3258, 44.68 3256, 44.59 3254, 44.55 3252, 44.51 3250, 44.46 3248, 44.41 3246, 44.33 3244, 44.24 3242, 44.19 3240, 44.13 3238, 44 3236, 43.88 3234, 43.83 3232, 43.79 3230, 43.74 3228, 43.66 3226, 43.6 3224, 43.51 3222, 43.43 3220, 43.43 3218, 43.41 3216, 43.29 3214, 43.17 3212, 43.09 3210, 43.04 3208, 42.96 3206, 42.87 3204, 42.81 3202, 42.78 3200, 42.72 3198, 42.64 3196, 42.55 3194, 42.48 3192, 42.46 3190, 42.42 3188, 42.34 3186, 42.29 3184, 42.24 3182, 42.18 3180, 42.14 3178, 42.05 3176, 41.93 3174, 41.88 3172, 41.83 3170, 41.76 3168, 41.72 3166, 41.68 3164, 41.66 3162, 41.61 3160, 41.53 3158, 41.46 3156, 41.47 3154, 41.44 3152, 41.37 3150, 41.34 3148, 41.39 3146, 41.41 3144, 41.4 3142, 41.38 3140, 41.36 3138, 41.35 3136, 41.38 3134, 41.44 3132, 41.46 3130, 41.46 3128, 41.48 3126, 41.54 3124, 41.54 3122, 41.54 3120, 41.6 3118, 41.66 3116, 41.71 3114, 41.79 3112, 41.89 3110, 42.01 3108, 42.08 3106, 42.14 3104, 42.23 3102, 42.34 3100, 42.43 3098, 42.56 3096, 42.69 3094, 42.77 3092, 42.84 3090, 42.95 3088, 43.06 3086, 43.13 3084, 43.24 3082, 43.37 3080, 43.49 3078, 43.61 3076, 43.74 3074, 43.91 3072, 44.04 3070, 44.13 3068, 44.25 3066, 44.37 3064, 44.48 3062, 44.58 3060, 44.67 3058, 44.81 3056, 44.92 3054, 45.01 3052, 45.14 3050, 45.23 3048, 45.31 3046, 45.46 3044, 45.57 3042, 45.65 3040, 45.78 3038, 45.9 3036, 45.96 3034, 46.03 3032, 46.16 3030, 46.26 3028, 46.34 3026, 46.46 3024, 46.57 3022, 46.66 3020, 46.75 3018, 46.84 3016, 46.91 3014, 46.98 3012, 47.05 3010, 47.17 3008, 47.32 3006, 47.44 3004, 47.51 3002, 47.58 3000, 47.65 2998, 47.71 2996, 47.78 2994, 47.86 2992, 47.91 2990, 47.99 2988, 48.11 2986, 48.22 2984, 48.31 2982, 48.41 2980, 48.45 2978, 48.45 2976, 48.52 2974, 48.62 2972, 48.71 2970, 48.8 2968, 48.87 2966, 48.96 2964, 49.02 2962, 49.05 2960, 49.09 2958, 49.12 2956, 49.2 2954, 49.33 2952, 49.4 2950, 49.42 2948, 49.46 2946, 49.51 2944, 49.57 2942, 49.61 2940, 49.62 2938, 49.63 2936, 49.67 2934, 49.71 2932, 49.71 2930, 49.7 2928, 49.72 2926, 49.78 2924, 49.87 2922, 49.93 2920, 50 2918, 50.12 2916, 50.26 2914, 50.36 2912, 50.43 2910, 50.5 2908, 50.58 2906, 50.66 2904, 50.73 2902, 50.82 2900, 50.88 2898, 50.93 2896, 50.97 2894, 51.01 2892, 51.08 2890, 51.16 2888, 51.28 2886, 51.34 2884, 51.36 2882, 51.43 2880, 51.5 2878, 51.55 2876, 51.61 2874, 51.67 2872, 51.7 2870, 51.77 2868, 51.87 2866, 51.89 2864, 51.87 2862, 51.91 2860, 51.95 2858, 51.95 2856, 51.98 2854, 52.03 2852, 52.07 2850, 52.17 2848, 52.31 2846, 52.4 2844, 52.47 2842, 52.53 2840, 52.59 2838, 52.67 2836, 52.76 2834, 52.82 2832, 52.87 2830, 52.94 2828, 53 2826, 53.04 2824, 53.11 2822, 53.16 2820, 53.17 2818, 53.22 2816, 53.31 2814, 53.36 2812, 53.37 2810, 53.41 2808, 53.46 2806, 53.56 2804, 53.65 2802, 53.65 2800, 53.65 2798, 53.72 2796, 53.8 2794, 53.82 2792, 53.83 2790, 53.87 2788, 53.96 2786, 54.04 2784, 54.08 2782, 54.11 2780, 54.17 2778, 54.2 2776, 54.25 2774, 54.32 2772, 54.36 2770, 54.42 2768, 54.47 2766, 54.5 2764, 54.52 2762, 54.55 2760, 54.6 2758, 54.68 2756, 54.75 2754, 54.76 2752, 54.78 2750, 54.86 2748, 54.95 2746, 54.99 2744, 54.99 2742, 55.04 2740, 55.11 2738, 55.15 2736, 55.18 2734, 55.19 2732, 55.24 2730, 55.31 2728, 55.36 2726, 55.39 2724, 55.44 2722, 55.5 2720, 55.52 2718, 55.55 2716, 55.6 2714, 55.65 2712, 55.69 2710, 55.74 2708, 55.8 2706, 55.84 2704, 55.85 2702, 55.91 2700, 55.99 2698, 56.02 2696, 56.07 2694, 56.1 2692, 56.12 2690, 56.16 2688, 56.21 2686, 56.26 2684, 56.3 2682, 56.31 2680, 56.33 2678, 56.42 2676, 56.5 2674, 56.56 2672, 56.61 2670, 56.66 2668, 56.69 2666, 56.72 2664, 56.73 2662, 56.79 2660, 56.83 2658, 56.87 2656, 56.92 2654, 56.96 2652, 57.01 2650, 57.03 2648, 57.07 2646, 57.12 2644, 57.14 2642, 57.18 2640, 57.24 2638, 57.28 2636, 57.31 2634, 57.35 2632, 57.41 2630, 57.43 2628, 57.46 2626, 57.53 2624, 57.58 2622, 57.61 2620, 57.61 2618, 57.61 2616, 57.66 2614, 57.73 2612, 57.76 2610, 57.79 2608, 57.83 2606, 57.87 2604, 57.93 2602, 57.98 2600, 58.02 2598, 58.04 2596, 58.05 2594, 58.08 2592, 58.12 2590, 58.15 2588, 58.2 2586, 58.26 2584, 58.31 2582, 58.35 2580, 58.38 2578, 58.42 2576, 58.45 2574, 58.44 2572, 58.49 2570, 58.55 2568, 58.55 2566, 58.58 2564, 58.65 2562, 58.72 2560, 58.76 2558, 58.75 2556, 58.76 2554, 58.82 2552, 58.86 2550, 58.89 2548, 58.94 2546, 58.95 2544, 58.94 2542, 58.96 2540, 59.01 2538, 59.07 2536, 59.09 2534, 59.12 2532, 59.15 2530, 59.2 2528, 59.22 2526, 59.22 2524, 59.24 2522, 59.26 2520, 59.3 2518, 59.35 2516, 59.38 2514, 59.39 2512, 59.42 2510, 59.47 2508, 59.5 2506, 59.56 2504, 59.62 2502, 59.67 2500, 59.66 2498, 59.64 2496, 59.67 2494, 59.72 2492, 59.74 2490, 59.78 2488, 59.81 2486, 59.84 2484, 59.88 2482, 59.89 2480, 59.9 2478, 59.93 2476, 59.96 2474, 59.96 2472, 59.96 2470, 60.02 2468, 60.09 2466, 60.07 2464, 60.09 2462, 60.15 2460, 60.18 2458, 60.21 2456, 60.25 2454, 60.27 2452, 60.3 2450, 60.33 2448, 60.32 2446, 60.32 2444, 60.36 2442, 60.4 2440, 60.41 2438, 60.41 2436, 60.46 2434, 60.52 2432, 60.56 2430, 60.61 2428, 60.64 2426, 60.62 2424, 60.61 2422, 60.62 2420, 60.65 2418, 60.67 2416, 60.71 2414, 60.79 2412, 60.8 2410, 60.78 2408, 60.79 2406, 60.81 2404, 60.85 2402, 60.85 2400, 60.87 2398, 60.92 2396, 60.95 2394, 60.98 2392, 60.98 2390, 61 2388, 61.07 2386, 61.14 2384, 61.21 2382, 61.26 2380, 61.26 2378, 61.23 2376, 61.15 2374, 61.06 2372, 61.01 2370, 61 2368, 60.94 2366, 60.86 2364, 60.83 2362, 60.78 2360, 60.7 2358, 60.7 2356, 60.69 2354, 60.65 2352, 60.76 2350, 61.03 2348, 61.3 2346, 61.36 2344, 61.16 2342, 61.04 2340, 61.02 2338, 61.05 2336, 61.15 2334, 61.26 2332, 61.26 2330, 61.2 2328, 61.2 2326, 61.31 2324, 61.37 2322, 61.33 2320, 61.34 2318, 61.43 2316, 61.53 2314, 61.58 2312, 61.57 2310, 61.56 2308, 61.59 2306, 61.65 2304, 61.73 2302, 61.8 2300, 61.82 2298, 61.85 2296, 61.91 2294, 61.92 2292, 61.93 2290, 62 2288, 62.03 2286, 62.05 2284, 62.1 2282, 62.12 2280, 62.12 2278, 62.11 2276, 62.13 2274, 62.14 2272, 62.16 2270, 62.16 2268, 62.16 2266, 62.18 2264, 62.25 2262, 62.31 2260, 62.3 2258, 62.27 2256, 62.28 2254, 62.34 2252, 62.37 2250, 62.37 2248, 62.39 2246, 62.4 2244, 62.38 2242, 62.4 2240, 62.43 2238, 62.46 2236, 62.48 2234, 62.47 2232, 62.47 2230, 62.5 2228, 62.56 2226, 62.59 2224, 62.59 2222, 62.61 2220, 62.62 2218, 62.61 2216, 62.6 2214, 62.63 2212, 62.68 2210, 62.72 2208, 62.74 2206, 62.77 2204, 62.76 2202, 62.74 2200, 62.75 2198, 62.78 2196, 62.8 2194, 62.82 2192, 62.82 2190, 62.82 2188, 62.85 2186, 62.89 2184, 62.93 2182, 62.95 2180, 62.92 2178, 62.88 2176, 62.9 2174, 62.91 2172, 62.89 2170, 62.91 2168, 62.94 2166, 62.95 2164, 62.94 2162, 62.97 2160, 63 2158, 62.99 2156, 63.02 2154, 63.02 2152, 63.01 2150, 63.03 2148, 63.05 2146, 63.02 2144, 63.03 2142, 63.08 2140, 63.08 2138, 63.07 2136, 63.09 2134, 63.11 2132, 63.13 2130, 63.14 2128, 63.15 2126, 63.15 2124, 63.12 2122, 63.17 2120, 63.18 2118, 63.17 2116, 63.2 2114, 63.2 2112, 63.2 2110, 63.19 2108, 63.21 2106, 63.25 2104, 63.26 2102, 63.24 2100, 63.24 2098, 63.24 2096, 63.24 2094, 63.27 2092, 63.26 2090, 63.23 2088, 63.21 2086, 63.24 2084, 63.27 2082, 63.26 2080, 63.28 2078, 63.29 2076, 63.29 2074, 63.3 2072, 63.3 2070, 63.27 2068, 63.3 2066, 63.35 2064, 63.32 2062, 63.29 2060, 63.32 2058, 63.33 2056, 63.31 2054, 63.3 2052, 63.3 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