The garnets constitute a group of minerals which share a
common structure. Common end member compositions are:
- Almandine ---------- Fe2+3Al2(SiO4)3
- Andradite ----------- Ca3Fe3+2(SiO4)3
- Grossular ----------- Ca3Al2(SiO4)3
- Pyrope -------------- Mg3Al2(SiO4)3
- Spessartite ---------- Mn3Al2(SiO4)3
- Uvarovite ----------- Ca3Cr2(SiO4)3
Other, less common end-member compositions are:
- Calderite ------------ Mn3Fe3+2(SiO4)3
- Goldmanite --------- Ca3V2(SiO4)3
- Hibschite ------------ Ca3Al2(SiO4)3-x(OH)4x
0.2 < x < 1.5
- Katoite -------------- Ca3Al2(SiO4)3-x(OH)4x
x > 1.5
- Kimzeyite ----------- Ca3(Zr,Ti)2((Si,Al,Fe3+)O4)3
- Knorringite ---------- Mg3Cr2(SiO4)3
- Majorite ------------- Mg3(Fe,Al,Si)2(SiO4)3
- Morimotoite -------- Ca3Ti4+Fe2+(SiO4)3
- Schorlomite --------- Ca3Ti4+2((Fe3+2Si)O4)3
Visible Spectra (generally 350 - 1100 nm)
As would be expected from a chemically complex group of
minerals, garnets owe their color to a variety of causes.
Absorption by Cr3+, V3+,
Fe3+
(6-coordinated site), Fe2+ (8-coordinated site),
Mn2+,
and Fe2+ - Ti4+
intervalence charge
transfer can all be found in the spectra of garnets.
-
Spectra of representative garnets
Colorless garnets
When devoid of transition metals such as
Mn, Fe, Cr, and V, grossular and pyrope garnets are colorless.
Dark red to pink garnets with Fe2+
Almandine, GRR 1056, Umba
River Valley, Tanzania, colored red by Fe2+; data file
Pyrope, GRR
131, unknown locality, probably Tanzania,
colored pink by Fe2+;. data
file
Vis-NIR region: Pyrope, GRR
83, rhodolite variety, Umba River Valley,
Tanzania, colored pink by Fe2+; data file
Pyrope, GRR 1121i, Wesselton, South Africa, Mg2.32 Mn0.01 Fe0.43 Ca0.27 Al1.95 Cr0.02, 1.693 mm thick; data file
Pyrope, GRR 1121f,
Wesselton, South Africa, 0.547 mm thick; data file
Orange garnets with Mn2+
- Spessartine, GRR
72, Rutherford Mine, VA, colored
orange by Mn2+ 3.45 mm thick; data
file
- Spessartine, GRR
43, Rutherford Mine, Amelia, VA,
colored orange by Mn2+, expanded view from a
2.165 mm thick sample. data file
- Pyrope-spessartine, GRR 1267,
Kenya, 1.686 mm thick; data file
Orange to black garnets with Fe2+, Fe3+
and
Ti4+
- Andradite, GRR
568, variety melanite (black when
thick), San Benito Mountains, California, with both Fe3+
and Ti4+, 0.102 mm thick. data
file
- Andradite (variety melanite), GRR 755, Santa Rita Peak,
San Benito Mountains, California. This garnet is black, but when
thinned, becomes dark brown-orange. The sharp peak near 441 nm is
from Fe3+; 0.045 mm thick, data file
- Grossular, GRR 1113,
(orange-brown), North Hill, Riverside, California. (Ca2.86 Fe0.12 Mn0.02) [Al1.52 Fe0.43 Ti0.05], with both Fe2+ and Fe3+, 0.336 mm thick. data file
- Grossular GRR 1386, (brown), Lalatema, Moshi, Kenya, 4.126 mm thick. Data file
Yellow-green garnets with Fe3+
- Andradite, GRR
48, Val Malenco, Sondrio Province, Italy, colored
greenish-yellow by Fe3+, 1.03 mm thick; data
file
- Grossular GRR1934b
from Sierra de las Cruces, near Lake Jaco, Chihuahua, Mexico, 2.60 mm thick.
This is a yellow-green rim on a crystal with a small black core.
Data file
Green garnets with V3+ and Cr3+
- Uvarovite,
GRR 1019, Jacksonville, California, colored green by Cr3+, 0.029 mm thick.
data file
- Grossular, variety Tsavorite, GRR
229, Tanzania,
colored green by V3+, 0.758 mm thick. data
file
- Andradite, variety demantoid, GIA 2952, Russia, 2.5 mm thick. The bright green garnet has both the features of Fe3+ and the features of Cr3+. Data file
Red garnets with Cr3+
- Red pyrope, GRR 1055, Moses Rock, Utah, Chromian-pyrope, Ca0.33 Mn0.02 Mg2.13 Fe0.54 Al1.95 Cr0.07, 0.840 mm thick; data file
Red and pink garnets with Mn3+
- Raspberry-red grossular GRR1890
from Sierra de Cruces Range, Coahuila, Mexico, 1.17 mm thick. Data File.
Blue to purple garnets
- Pyrope, GRR
2224, Tunduru, Tanzania. This is a color-change garnet that goes from pale purplish-blue to light purple depending upon the
illumination, 2.426 mm. Data
file.
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updated 20-Jun-06