H in Olivine

Updated 6-Jul-2023 by GR Rossman

1970s

Wilkins RWT, Sabine W (1973) Water content of some nominally anhydrous silicates. American Mineralogist 58, 508–516.

1980s

Beran A, Putnis A (1983) A model of the OH position in olivine, derived from infrared spectroscopy investigations. Physics and Chemistry of Minerals 9, 57–60.
Aines RD, Rossman GR (1984) Water in minerals? A peak in the infrared. Journal of Geophysical Research 89, 4059-4072.
Mackwell SJ, Kohlstedt DL, Paterson MS (1985) The role of water in the deformation of olivine single crystals. Journal of Geophysical Research, B 90, 11319-11333.
Freund F, Oberheuser G (1986) Water dissolved in olivine: a single crystal infrared study. Journal of Geophysical Research 91, 745-761.
Miller GH, Rossman GR, Harlow GE (1987) The natural occurrence of hydroxide in olivine. Physics and Chemistry of Minerals 14, 461-472.
Kitamura M, Kondoh S, Morimoto N, Miller GH, Rossman GR, Putnis A (1987) Planar OH-bearing defects in mantle olivine. Nature 328, 143-145.

1990s

Mackwell SJ, Kohlstedt DL (1990) Diffusion of hydrogen in olivine: implications for water in the mantle. Journal of Geophysical Research 95, 5079–5088.
Bai Q, Kohlstedt DL (1992) Substantial hydrogen solubility in olivine and implications for water storage in the mantle. Nature, 357, 672-674.
Bell DR, Rossman GR (1992) Water in Earth's Mantle: the role of nominally anhydrous minerals. Science 255, 1391-1397
Kurosawa M, Yurimoto H, Matsumoto K, Sueno S (1992) Hydrogen analysis of mantle olivine by secondary ion mass spectrometry. In: Syono, Manghnani MH (eds) High-Pressure Research in Mineral Physics: Application to Earth and Planetary Sciences. pp. 283–287. Terra Pub-Am Geophys Union, Tokyo/Washington DC.
Kurosawa M, Yurimoto H, Matsumoto K, Sueno S (1992) Quantitative analysis of H, Ca and Ni in olivine by secondary ion mass spectrometry. Annual Report Institute Geoscience University Tsukuba 18, 83–89.
Bai Q, Kohlstedt DL (1993) Effects of chemical environment on the solubility and incorporation mechanism for hydrogen in olivine. Physics and Chemistry of Minerals 19, 460–471
Fujimoto K, Fukutani K, Tsunoda M, Yamashita H, Kobayashi K (1993) Hydrogen depth profiling using ¹H(¹⁵N,ɑ-γ)¹²C resonant nuclear-reaction on water-treated olivine surfaces and characterization of hydrogen species. Geochemical Journal 27, 155-162.
Kurosawa M, Yurimoto H, Matsumoto K, Sueno S (1993) Water in Earth’s mantle: hydrogen analysis of mantle olivine, pyroxenes and garnet using the SIMS. Proc Lunar Planet Sci Conf 24th, 839–840.
Sykes D, Rossman GR, Veblen DR, Grew ES (1994) Enhanced hydrogen and fluorine incorporation in borian olivine. American Mineralogist 79, 904-908.
Wright K, Catlow CRA (1994) A computer simulation study of (OH) defects in olivine. Physics and Chemistry of Minerals 20, 515–518.
Kohn (1995) Solubility of H₂O in nominally anhydrous mantle minerals using ¹H MAS NMR. American Mineralogist 81, 1523-1526.
Libowitzky E & Beran A (1995) OH defects in forsterite. Physics and Chemistry of Minerals 22, 387–392.
Kohlstedt DL, Keppler H, Rubie DC (1996) Solubility of water in the α, β and γ phases of (Mg, Fe)₂SiO₄. Contributions to Mineralogy and Petrology 123, 345–357.
Haiber M, Ballone P, Parrinello M (1997) Structure and dynamics of protonated Mg₂SiO₄: An ab-initio molecular dynamics study. American Mineralogist 82, 913-922.
Kurosawa M, Yurimoto H, Sueno S (1997) Patterns in the hydrogen and trace element compositions of mantle olivines. Physics and Chemistry of Minerals 24, 385-395
Sweeney RJ, Prozesky VM, Springhorn KA (1997) Use of the elastic recoil detection analysis (ERDA) microbeam technique for the quantitative determination of hydrogen in materials and hydrogen partitioning between olivine and melt at high pressures. Geochimica et Cosmochimica Acta 61, 101-113.
Kohlstedt DL, Mackwell SJ (1998) Diffusion of Hydrogen and Intrinsic Point Defects in Olivine. Zeitschrift für Physikalische Chemie 207, 147-162.
Kohn SC (1998) ¹H MAS NMR studies of water solubilities and dissolution mechanisms in olivine, clinopyroxene and orthopyroxene. Mineralogical Magazine 62, 799-800.

2000s

Brodholt JP, Refson K (2000) An ab initio study of hydrogen in forsterite and a possible mechanism for hydrolytic weakening. Journal of Geophysical Research, 105, 18977-18982.
Ingrin J, Skogby H (2000) Hydrogen in nominally anhydrous upper-mantle minerals: concentration levels and implications. European Journal of Mineralogy 12, 543-570.
Keppler H, Rauch M (2000) Water solubility in nominally anhydrous minerals measured by FTIR and ¹H MAS NMR: the effect of sample preparation. Physics and Chemistry of Minerals 27, 371-376.
Khisina NR, WIrth R, Andrut M, Uhanov AV (2001) Extrinsic and intrinsic mode of hydrogen occurrence in natural olivines: FTIR and TEM investigation. Physics and Chemistry of Minerals 28, 291-301.
Matveev S, O’Neill HSC, Ballhaus C, Taylor WR, Green DH (2001) Effect of silica activity on OH−IR spectra of olivine: implications for low-alpha SiO₂ mantle metasomatism. Journal of Petrology 42,721–729.
Kent AJR, Rossman GR (2002) Effect of hydroxyl content on lithium and boron in olivine. American Mineralogist 87, 1432-1436.
Khisina NR, Wirth R (2002) Hydrous olivine (Mg_1-xFe²⁺_y)_2-xV_xSiO₄H_2x - a new DHMS phase of variable composition observed as nanometer-sized precipitations in mantle olivine. Physics and Chemistry of Minerals 29, 98-111.
Smyth JR, Frost DJ (2002) The effect of water on the 410-km discontinuity: An experimental study. Geophysical Research Letters 29, 1485-014418

2003

Bell DR, Rossman GR, Maldener J, Endish D, Rauch F (2003) Hydroxide in olivine: A quantitative determination of the absolute amount and calibration of the IR spectrum. Journal of Geophysics Resarch 108, 2105-2113.
Beran A, Libowitzky E (2003) IR spectroscopic characterization of OH defects in mineral phases. Phase Transitions 76, 1-15.
Braithwaite JS, Wright K, Catlow CRA (2003) A theoretical study of the energetics and IR frequencies of hydroxyl defects in forsterite. Journal of Geophysical Research 108, 2284.
Churakov SV, Khisina NR, Urusov VS, WIrth R (2003) First-principles study of (MgH₂SiOs)•n(Mg₂SiO₄) hydrous olivine structures. I. Crystal structure modelling of hydrous olivine H_y-2a(MgH₂SiO₄)•3(SiO₄). Physics and Chemistry of Minerals 20, 1-11.
Demouchy S, Mackwell S (2003) Water diffusion in synthetic iron-free forsterite. Physics and Chemistry of Minerals 30, 486-494.
Koga K, Hauri E, Hirschmann M, Bell D (2003) Hydrogen concentration analyses using SIMS and FTIR: Comparison and calibration for nominally anhydrous minerals. Geochemistry Geophysics Geosystems 4, 1019

2004

Aubaud C, Hauri E, Hirschmann MM (2004) Hydrogen partition coefficients between nominally anhydrous minerals and basaltic melts. Geophysical Research Letters 31, L20611.
Bell DR, Rossman GR, Moore RO (2004) Abundance and Partitioning of OH in a High-pressure Magmatic System: Megacrysts from the Monastery Kimberlite, South Africa. Journal of Petrology 45, 1539–1564.
Lemaire C, Kohn SC, Brooker RA (2004) The effect of silica activity on the incorporation mechanisms of water in synthetic forsterite: a polarised infrared spectroscopoic study. Contributions to Mineralogay and petrology 147, 48-57
Matsyuk SS, Langer K (2004) Hydroxyl in olivines from mantle xenoliths in kimberlites of the Siberian platform. Contributions to Mineralogy and Petrology 147, 413-437.
Matveev S, Portnyagin M, Ballhaus C, Brooker R, Geiger CA (2004) FTIR Spectrum of Phenocryst Olivine as an Indicator of Silica Saturation in Magmas. Journal of Petrology 46, 1093
Wang Z, Hiraga T, Kohlstedt DL (2004) Effect of H+ on Fe-Mg interdiffusion in olivine, (Fe,Mg)₂SiO₄. Applied Physics Letters 85, 209-211.
Zhao Y-H, Ginsberg SB, Kohlstedt DL (2004) Solubility of hydrogen in olivine: dependence on temperature and iron content. Contrib Mineral Petrol 147, 155–161

2005

Berry A, Hermann J, O’Neill HSC, Foran GJ (2005) Fingerprinting the water site in mantle olivine. Geology 33, 869–872.
Frost DJ, SMyth JR (2005) The effects of temperature and water concentration on the olivine to wadsleyite transformation. Geophysical Research Abstracts 7, 06398.
Matveev S, Portnyagin M, Ballhaus C, Brooker R, Geiger CA. (2005) FTIR Spectrum of Phenocryst Olivine as an Indicator of Silica Saturation in Magmas. Journal of Petrology, 46, 603-614.

2006

Asimow PD, Stein LC, Mosenfelder JL, Rossman GR (2006) Quantitative polarized infrared analysis of trace OH in populations of randomly oriented mineral grains. American Mineralogist 91, 278-284.
Beran A & Libowitzky E (2006). Water in natural mantle minerals II: olivine, garnet and accessory minerals. In: Keppler H & Smyth HR (eds) Water in Nominally Anhydrous Minerals. Chantilly, VA: Mineralogical Society of America, pp. 169–191.
Demouchy S, Jacobsen SD, Gaillard F, Stern CR (2006) Rapid magma ascent recorded by water diffusion profiles in mantle olivine. Geology 34, 429-432.
Demouchy S, Mackwell S (2006) Mechanisms of hydrogen incorporation and diffusion in iron-bearing olivine. Physics and Chemistry of Minerals 33, 347–355.
Grant KJ, Kohn SC, Brooker RA (2006) Solubililty and partitioning of water in synthetic forsterite and enstatite in the system MgO-SiO₂-H₂O +/- Al₂O₃. Contributions to Mineralogay and petrology 151, 651-664.
Katayama I, Nakashima S, Yurimoto H (2006) Water content in natural eclogite and implication for water transport into the deep upper mantle Lithos 86, 245-259.
Koch-Muller M, Matsyuk SS, Rhede D, Wirth R, Khisina N (2006) Hydroxyl in mantle olivine xenocrysts from the Udachnaya kimberlite pipe.Physics and Chemistry of Minerals 33, 276-287.
Mosenfelder JL, Deligne NI, Asmiow PD, Rossman GR (2006) Hydrogen incorporation in olivine from 2-12 GPa. American Mineralogist 91, 285–294.
Mosenfelder JL, Sharp TG, Asimow PD, Rossman GR (2006) Hydrogen incorporation in natural mantle olivines. AGU monograph 168 p45-83.
Peslier AH, Lurh JF (2006) Hydrogen loss from olivines in mantle xenoliths from Simcoe (USA) and Mexico: Mafic alkalic magma ascent rates and water budget of the sub-continental lithosphere. Earth and Planetary Science Letters 242, 302–319.
Smyth JR, Frost DJ, Nestola F, Holl CM, Bromiley G (2006) Olivine hydration in the deep upper mantle: effects of temperature and silica activity. Geophysical Research Letters 33(15) L15301.
Walker AM, Demouchy S, Wright K (2006) Computer modelling of the energetics and vibrational properties of hydroxyl groups in α-and β-Mg₂SiO₄. European Journal of Mineralogy, 18, 529-543.

2007

Aubaud C. Withers AC, Hirschmann MM, Guan Y, Leshin LA, Mackwell SJ, Bell DR (2007) Intercalibration of FTIR and SIMS for hydrogen measurements in glasses and nominally anhydrous minerals. American Mineralogist 92, 811–828.
Berry AJ, O’Neill HSC, Hermann J, Scott DR (2007) The infrared signature of water associated with trivalent cations in olivine. Earth and Planetary Science Letters 261, 134-142.
Berry A, Walker AM, Hermann J, O’Neill HStC, Foran GJ, Gale J (2007) Titanium substitution mechanisms in forsterite. Chemical Geology242, 176–186.
Grant K, Ingrin J, Loran J-P, Dumas P (2007) Water partitioning between mantle minerals from peridotite xenoliths. Contribution to Mineralogy and Petrology 154, 15-34
Grant KJ, Kohn SC, Brooker RA (2007) The partitioning of water between olivine, orthopyroxene and melt synthesised in the system albite-forsterite-H₂O. Earth and Planetary Science Letters 260, 227-241
Grant KJ, Brooker RA, Kohn SC, Wood BJ (2007) The effect of oxygen fugacity on hydroxyl concentrations and speciation in olivine: Implications for water solubility in the upper mantle. Earth and Planetary Sciences Letters 261, 217-229.
Litasov KD, Ohtani E, Kagi H, Jacobsen SD (2007) Temperature dependence and mechanism of hydrogen incorporation in olivine at 12.5-14.0 GPa. Geophysical Research Letters 34, L16314.
Matveev S, Stachel T (2007) FTIR spectroscopy of OH in olivine: A new tool in kimberlite exploration. Geochimica et Cosmochimica Acta 71, 5528-5543.
Shaw DM, Tse JS (2007) Vibrational dynamics of H+-substituted forsterite: A first-principles molecular dynamics study. American Mineralogist 92 1593-1600.
Walker AM, Hermann J, Berry AJ, O’Neill HSC (2007) Three water sites in upper mantle olivine and the role of titanium in the water weakening mechanism. Journal of Geophysical Research 112(B5).

2008

Balan E, Refson K, Blanchard M, Delattre S, Lazzeri M, Ingrin J, Mauri F, Wright K, Winkler, B. (2008) Theoretical infrared absorption coefficient of OH groups in minerals. American Mineralogist, 93, 950-953.
Bali E, Bolfan-Casanova N, Koga KT (2008) Pressure and temperature dependence of H solubility in forsterite: an implication to water activity in the Earth interior. Earth and Planetary Science Letters 268, 354–363.
Gose J, Reichart P, Dollinger G & Schmäicke E (2008) Water in natural olivine - determined by proton-proton scattering analysis. American Mineralogist 93, 1613–1619.
Khisina N, Wirth R, Matsyuk S, Koch-Muller M (2008) Microstructures and OH-bearing nano-inclusions in “wet” olivine xenocrysts from the Udachnaya kimberlite. European Journal of Mineralogh 20, 1067-1078.
Kudoli Y (2008) Crystal structural features of hvdrous forsterite: Effect of Fe on the M-site vacancies, possible hydrogen positions and variation of the unit cell dimensions. Journal of Mineralogy Petrological Science 103, 371-375.
Li ZXA, Lee CTA, Peslier AH, Lenardic A, Mackwell SJ (2008) Water contents in mantle xenoliths from the Colorado Plateau and vicinity: Implications for the mantle rheology and hydration-induced thinning of continental lithosphere Journal of Geophysical Research 113. B09210.
Peslier AH, Woodland AB, Wolff JA (2008) Fast kimberlite ascent rates estimated from hydrogen diffusion profiles in xenolithic mantle olivines from southern Africa. Geochimica et Cosmochimica Acta 72, 2711-2722.
Withers AC, Hirschmann MM (2008) Influence of temperature, composition, silica activity and oxygen fugacity on the H₂O storage capacity of olivine at 8 GPa.
Contrib Mineral Petrol 156, 595–605.
Yang X, Xia Q, Deloule E, Dalllai L, Fan Q, Feng M (2008) Water in minerals of the continental lithospheric mantle and overlying lower crust: A comparative study of peridotite and granulite xenoliths from the North China Craton. Chemical Geology 256, 33-45.

2009

Aubaud C, Bureau H, Raepsaet C, Khodja H, Withers AC, Hirschmann MM, Bell DR (2009) Calibration of the infrared molar absorption coefficients for H in olivine, clinopyroxene and rhyolitic glass by elastic recoil detection analysis. Chemical Geology 260, 286–294.
Bureau H, Raepsaet C, Khodja H, Carraro A, Aubaud C (2009) Determination of hydrogen content in geological samples using elastic recoil detection analysis (ERDA). Geochimica et Cosmochimica Acta 73, 3311–3322.
Hushur A, Manghnani MH, Smyth JR, Nestola F, Frost DJ (2009) Crystal chemistry of hydrous forsterite and its vibration properties up to 41 GPa. American Mineralogist 94, 751–760.
Kovacs I, O'Neill HSC, Hermann J, Hauri E (2009) O-H absorption coefficients of four comon mechanisms for water substitution in olivine. Goldschmidt Conference Abstracts 2009, A690.
Litasov KD, Ohtani E, Kagi H, Jacobsen SD (2007) Temperature dependence and mechanism of hydrogen incorporation in olivine at 12.5-14.0 GPa. Geophysical Research Letters 34, L16314.
Peslier AH, Woodland AB, Bell DR, Lazarov M (2010) Olivine water contents in the continental lithosphere and the longevity of cratons. Nature 467, 78–81.
Tenner TJ, HIrschmann MM, Withers AC, Hervig RL (2009) Hydrogen partitioning between nominally anhydrous upper mantle minerals and melt between 3 and 5 GPa and applications to hydrous peridotite partial melting. Chemical Geology 26, 42-56.
Thomas SM, Koch-Muller M, Reichart P, Rhede D, Thomas R, WIrth R, Matsyuk S (2009) IR calibrations for water determination in olivine, r-GeO₂, and SiO₂ polymorphs. Physics and Chemistry of Minerals 36, 489-509.

2010

Gose J, Schmadicke E, Markowitz M, Beran A (2010) OH point defects in olivine from Pakistan. Mineralogy Petrology 99, 105-111.
Kovács I, O’Neill HSC, Hermann J & Hauri EH (2010) Site-specific infrared O-H absorption coefficients for water substitution into olivine. American Mineralogist 95,292–299.
Peslier AH, Woodland AB, Bell DR, Lazarov M (2010) Olivine water contents in the continental lithosphere and the longevity of cratons. Nature 467, 78-83.
Xia QK, Hao Y, Li P, Deloule E, Coltorit M, Dallai L, Yang X, Feng M (2019) Low water content of the Cenozoic lithospheric mantle beneath the eastern part of the North China Craton. Journal of Geophysical Research 115, B07207.
Zhang F, Wright K (2010) Coupled (H⁺,M³⁺) substitutions in forsterite. Geochimica et Cosmochimica Acta 74, 5958-5965.

2011

Balan E, Ingrin J, Delattre S, Kovács I, Blanchard M (2011) Theoretical infrared spectrum of OH-defects in forsterite. Eur J Mineral 23(3):285–292.
Mosenfelder JL. Le Voyer, Rossman GR, Guan Y, Bell DR, Asimow PD, Eiler JM (2011) Analysis of hydrogen in olivine by SIMS: evaluation of standards and protocol. American Mineralogist 96, 1725–1741.
Otsuka K, Karato S-I (2011) Control of the water fugacity at high pressures and temperatures: applications to the incorporation mechanisms of water inolivine. Phys Earth Planet Inter 189, 27–33.
Umemoto K, Wentzcovitch RM, Hirschmann MM, Kohlstedt DL, Withers AC (2011) A first-principles investigation of hydrous defects and IR frequencies in forsterite: The case for Si vacancies. Am Mineral 96, 1475–1479.
Withers AC, Hirschmann MM, Tenner TJ (2011) The effect of Fe on olivine H₂O storage capacity: Consequences for H₂O in the Martian mantle. American Mineralogist 96, 1039-1053.
Yang X, Keppler H (2011) In-situ infrared spectra of OH in olivine to 1100 C. American Mineralogist 96, 451-454.

2012

Ardia P, Hirschmann MM, Withers AC, Tenner TJ (2012) H₂O storage capacity of olivine at 5–8 GPa and consequences for dehydration partial melting of the upper mantle. Earth and Planetary Science Letters 2435-348, 104-116
Férot A, Bolfan-Casanova N (2012) Water storage capacity in olivine and pyroxene to 14 GPa: implications for the water content of the Earth’s upper mantle and nature of seismic discontinuities. Earth and Planetary Science Letters 349–350:218–230
Kovács I, Green D, Rosenthal A, Hermann J, O’Neil HStC, Hibberson WO, Udvardi B (2012) An experimental study of water in Nominally Anhydrous Minerals in the upper mantle near the water-saturated solidus. Journal of Petrology 53, 2067-2093.
Withers AC, Bureau H, Raepsaet C, Hirschmann MM (2012) Calibration of infrared spectroscopy by elastic recoil detection analysis of H in synthetic olivine. Chemical Geology 334, 92-98
Zhang F, Wright K (2012) Coupled (Li⁺, Al³⁺) substitutions in hydrous forsterite. American Mineralogist 97, 425429.

2013

Ingrin J, Liu J, Depecker C, Kohn SC, Balan E, Grant KJ (2013) Low-temperature evolution of OH bands in synthetic forsterite, implication for the nature of H defects at high pressure. Phys Chem Miner 40(6):499–510
Schmädicke E, Gose J, Witt-Eickschen G & Brätz H (2013) Olivine from spinel peridotite xenoliths: hydroxyl incorporation and mineral composition. American Mineralogist 98,1870–1880.
Hao Y,Xia Q, Liu S, Gu X, Feng M, Zhang Y (2013) Recognizing juvenile and relict lithospheric mantle beneath the North China Craton: Combined analysis of H₂O, major and trace elements and Sr–Nd isotope compositions of clinopyroxenes. Lithos 149, 136-145.
Xia Q, Hao Y, Liu S, Gu X, Feng Hao Y,Xia Q, Liu S, Gu X, Feng M, Zhang Y (2013) Recognizing juvenile and relict lithospheric mantle beneath the North China Craton: Combined analysis of H₂O, major and trace elements and Sr–Nd isotope compositions of clinopyroxenes. Lithos 149, 136-145.
Xia Q, Hao Y, Liu SC, Gu XY, Feng M (2013) Water contents of the Cenozoic lithospheric mantle beneath the western part of the North China Craton: Peridotite xenolith constraints. Gondwana Research 23, 108-118.

2014

Balan E, Blanchard M, Lazzeri M, Ingrin J (2014) Contribution of interstitial OH groups to the incorporation of water in forsterite. Physics and Chemistry of Minerals 41, 105-114.
Bolfan-Casanova N, Montagnac G, Reynard B (2014) Measurement of water contents in olivine using Raman spectroscopy.American Mineralogist 99, 149-156.
Crépisson C, Blanchard M, Bureau H, Sanloup C, Withers AC, Khodja H, Surblé S, Béneut K, Leroy C, Giura P, Balan E (2014) Clumped fluoride-hydroxyl defects in forsterite: Implications for the upper-mantle. Earth and Planetary Science Letters, 390, 287-295.
Crépisson C, Bureau H, Blanchard M, Ingrin J, Balan E (2014) Theoretical infrared spectrum of partially protonated cationic vacancies in forsterite. European Journal of Mineralogy, 26, 203-210.
Dudnikova VB, Urusov VS (2014) Simulation of Forsterite Protonation by the Interatomic Potential Method. Geochemistry International 52, 261–270. Translated from Geokhimiya, 2014, 52, 291–301.
Gaetani GA, O'Leary JA, Koga KT, Hauri EH, Rose-Koga EF, Monteleone BD (2014) Hydration of mantle olivine under variable water and oxygen fugacity conditions. Contributions to Mineralogy and Petrology 167, 965-979.
Hilchie L, Fedortchouk Y, Matveev S, Kopylova MG (2014) The origin of high hydrogen content in kimberlitic olivine: Evidence from hydroxyl zonation in olivine from kimberlites and mantle xenoliths. Lithos 202-203, 429-441.
Ingrin J, Kovács I, Deloule E, Balan E, Blanchard M, Kohn SC, Hermann J (2014) Identification of hydrogendefects linked to boron substitution in synthetic forsterite and natural olivine. American Mineralogist 99, 2138–2141.
Padrón-Navarta JA, Hermann J, O’Neill HSC (2014) Site-specific hydrogen diffusion rates in forsterite. Earth and Planetary Science Letters, 392, 100–112
Shen T, Hermann J, Zhang L, Padrón-Navarta JA, Chen J (2014) FTIR spectroscopy of Ti-chondrodite, Ti-clinohumite, and olivine in deeply subducted serpentinites and implications for the deep water cycle.Contrib Mineral Petrol 167, 992–1009.
Wang Q, Bagdassarov N, Xia Q, Zhu B (2014) Water contents and electrical conductivity of peridotite xenoliths from the North China Craton: Implications for water distribution in the upper mantle. Lithos 189, 105-126.
Wang Q, Bagdassarov N, Xia Q, Zhu B (2014) Water contents and electrical conductivity of peridotite xenoliths from the North China Craton: Implications for water distribution in the upper mantle. Lithos 189, 105-126.Yang X, Liu D, Xia Q (2014) CO₂-induced small water solubility in olivine and implications for properties of the shallow mantle. Earth Planet Sci Lett 403, 37–47.

2015

Baptise V, Domouchy S, Keshav S, Parat F, Bolfan-Casanova N, Condamine P, Cordier P (2015) Decrease of hydrogen incorporation in forsterite from CO₂-H₂O-rich kimberlitic liquid. American Mineralogist 100, 1912-1920.
Freund FT, Freund MM (2015) From Where Did the Water Come That Filled the Earth’s Oceans? A Widely Overlooked Redox Reaction. American Journal of Analytical Chemistry 6, 342-349.
Karato S (2015) Some notes on hydrogen-related point defects and their role in theisotopi exchange and electrical conductivity in olivine. Physics of the Earth and Planetary interiors 248, 94-98.
Novella D, Bolfan-Casanova N, Nestola F, Harris JW (2015) H₂O in olivine and garnet inclusions still trapped in diamonds from the Siberian craton: Implications for the water content of cratoniclithosphere peridotites. Lithos 230, 180-183.
Tollan PME, O'Neill HSC, Hermann J, Benedictus A, Arculus RJ (2015) Frozen melt–rock reaction in a peridotite xenolith from sub-arc mantle recorded by diffusion of trace elements and water in olivine. Earth and Planetary Science Letters 422, 169-181

2016

Demouchy S, Bolfan-Casanova N (2016) Distribution and transport of hydrogen in the lithospheric mantle: A review. Lithos 240-243, 402-425.
Faul U, Cline CJ, David EC, Berry AJ, Jackson I (2016) Titanium-hydroxyl defect-controlled rheology of the Earth’s upper mantle. Earth and Planetary Science Letters, 452, 227–237.
Jollands MC, Padrón-Navarta JA, Hermann J, O’Neill HSC (2016) Hydrogen diffusion in Ti-doped forsterite and the preservation of metastable point defects. Am Mineral 101(7–8):1571–1583
Nestola F, Smyth JR (2016) Diamonds and water in deep Earth: a new scenario. International Geology Reviews 58, 263-276.
Yang X (2016) Effect of oxygen fugacity on OH dissolution in olivine under peridotite-saturated conditions: An experimental study at 1.5-7 GPa and 1100-1300°C. Geochimica et Cosmochimica Acta, 173, 319-336.

2017

Balan E, Blanchard M, Lazzeri M, Ingrin J (2017) Theoretical Raman spectrum and anharmonicity of tetrahedral OH defects in hydrous forsterite. European Journal of Mineralogy 29, 201–212.
Blanchard M, Ingrin J, Balan E, Kovacs I, Withers AC (2017) Effect of iron and trivalent cations on OH defects in olivine. American Mineralogist 102, 302–311.
Grutzner T, Kohn SC, BBromiley DW, Rohrbach A, Berndt J, Klemme S (2017) The storage capacity of fluorine in olivine and pyroxene under upper mantle conditions. Geochimica et Cosmochimica Acta 208, 160-170.
Shuai K, Yang X (2017) Quantitative analysis of H-species in anisotropoic minerals by polarized infrared spectroscopy along three orthogonal directions. Contributions to Mineralogy and Petrology 172, 14
Padrón-Navarta JA, Hermann J (2017) A subsolidus olivine water solubility equation for the Earth’s upper mantle. Journal of Geophysical Research: Solid Earth 122, 9862–9880.
Tollan PME, Smith R, O'Neill HSC, Hermann (2017) The responses of the four main substitution mechanisms of H in olivine to H2O activity at 1050 °C and 3 GPa. Progress in Earth and Planetary Science 4, 14.
Xue X, Kanzaki M, Turner D, Loroch D (2017) Hydrogen incorporation mechanisms in forsterite: New insights from ¹H and ²⁹Si NMR spectroscopy and first-principles calculation. American Mineralogist 102, 519–536

2018

Babushkina MS, Ugolkov VL, Marin YB, Nikitina LP, Goncharov AG (2018) Hydrogen and Carbon Groups in the Structures of Rock-Forming Minerals of Rocks of the Lithospheric Mantle: FTIR and STA plus QMS Data. Docklady Earth Sciences 479, 456-459.
Ferriss E, Plank T, Newcommbe M, Walker D, Hauri E (2018) Rates of dehydration of olivines from San Carlos and Kilauea Iki. Geochimica et Cosmochimica Acta 242, 165-190.
Jackson A, Parker RL, Sambridge M, Constable C, WoLf AS (2018) The inverse problem of unpolarized infrared spectroscopy of geological materials:
Estimation from noisy random sampling of a quadratic form. American Mineralogist 103, 1176–1184.
Kempf ED, Hermann J (2018) Hydrogen incorporation and retention in metamorphic olivine during subduction: Implications for the deep water cycle Geology 46, 571–574.
Li P, Scott JM, Liu J, Xia Qk (2018) Lateral H₂O variation in the Zealandia lithospheric mantle controls orogen width. Earth and Planetary Science Letters 502, 200-209.
Qin, T., Wentzcovitch, R. M., Umemoto, K., Hirschmann, M. M., & Kohlstedt, D. L. (2018). Ab initio study of water speciation in forsterite:Importance of the entropic effect. American Mineralogist, 103(5), 692–699.
Sokol AG, Kupriyanov IN, Tomilenko AA, Bul'bak TA, Palyanov YuN, Sobolev NV (2018) Formation of Water-Bearing Defects in Olivine in the Presence of Water-Hydrocarbon Fluid at 6.3 GPa and 1200°C. Doklady Earth Sciences 483), 1451-1453.
Thoraval, C., Demouchy, S., and Padrón, J.A. (2018) Relative diffusivities of hydrous defects from partially dehydrated natural olivine. Physics and Chemistry of Minerals.
Tollan PME, O'Neill HSC, Hermann J (2018) The role of trace elements in controlling H incorporation in San Carlos olivine. Contributions to mineralogy and petrology 173, 89.
Qin T, Wentzcovitch RM, Umemoto K, Hirschmann MM, Kohlstedt DL (2018) Ab initio study of water speciation in forsterite: Importance of the entropic effect. American Mineralogist 103, 692–699.

2019

Del Vecchio A, Poe BT, Wang Q, Bagdassarov N, Xia Q, ZhuXia Q, Hao Y, Liu S, Gu X, Feng M (2013) Water contents of the Cenozoic lithospheric mantle beneath the western part of the North China Craton: Peridotite xenolith constraints. Gondwana Research 23, 108-118.
Demouchy S, Tommasi A, Ionov D, Higgie, K, Carlson RW (2019) Microstructures, water contents, andseismic properties of the mantle lithosphere beneath the northern limit of the Hangay Dome, Mongolia. Geochemistry, Geophysics, Geosystems,20, 183–207.
Karato SI (2019) Some remarks on hydrogen-assisted electrical conductivity in olivine and other minerals. Progress in Earth and Planetary Science 6, 55.
Liu D, Wang S, Smygh JR, Zhang J, Wang X, ZHu X, Ye Y (2019) In Situ Infrared Spectra for Hydrous Forsterite up to 1243 K: Hydration Effect on Thermodynamic Properties. Minerals 9, 512.
Misiti V, Guidi MC (2019) High-Temperature Evolution of Point Defect Equilibria in Hydrous Forsterite Synthesized at1100 ºC and up to 4 GPA. Minerals 9, 574.
Schaffer LA, Peslier AH, Brandon AD, Bizimis M, Gibler R, Norman N, Harvey J (2019) Effects of melting, subduction-related metasomatism, and sub-solidus equilibration on the distribution of water contents in the mantle beneath the Rio Grande Rift.Geochimica et Cosmochimica Acta 266, 351-381.
Xu Y, Tang W, Hui H, Rudnick RL, Shang S, Zhang Z (2019 Reconciling the discrepancy between the dehydration rates in mantle olivine and pyroxene during xenolith emplacement. Geochimica et Cosmochimica Acta 267, 179–195.
Yang Y, Liu W, Qi Z, Wang ZP, Smyth JR, Xia Q (2019) Re-configuration and interaction of hydrogen sites in olivine at high temperature and high pressure. American Mineralogist 104, 878-889.
Yu M, Wang Q, Yang J (2019) Fabrics and water contents of peridotites in the Neotethyan Luobusa ophiolite, southern Tibet: implications for mantle recycling in supra-subduction zones. Journal of the Geological Society 176, 975-991.
Zhang WF, Xia XP, Eiichi T, Li L, Yang Q, Zhang YQ, Yang YN, Liu ML, Lai C (2019) Optimization of SIMS analytical parameters for water content measurement of olivine. Surface and Interface A,alysis 52, 224-233.

2020

Doucet LS, Xu YJ, Klaessens D, Hui HJ, Ionov DA, Mattielli N (2020) Decoupled water and iron enrichments in the cratonic mantle: A study on peridotite xenoliths from Tok, SE Siberian Craton. American Mineralogist 105, 803-819.
Fei H, Druzhbin D, Katsura T (2020) The Effect of Water on Ionic Conductivity in Olivine. Journal of Geophysical Research: Solid Earth 125,e2019JB019313.
Fei H, Katsura T (2020) Pressure Dependence of Proton Incorporation and Water Solubility in Olivine. Journal of Geophysical Research: Solid Earth 125, e2019JB018813.
Newcombe ME, Plank T, Barth A, Asimow PD, Hauri E (2020) Water-in-olivine magma ascent chronometry: Every crystal is a clock. Journal of Volcanology and Geothermal Research 398, article 106872.
Wang Y, He M, Yan W, Yang M, Liu X (2020) Jianite: Massive Dunite Solely Made of Virtually PureForsterite from Ji’an County, Jilin Province,Northeast China. Minerals 10, 220

2022

Nformidah-Ndah SS, Tollan PME, Hermann J, Chouankoue JP (2022) Depletion and refertilisation of the lithospheric mantle below the Kapsiki plateau (Northern Cameroon Volcanic Line) deduced from trace element and H2O systematics in mantle xenoliths. Journal of African Earth Sciences 189, 104483
Yang L, Maackwell SJ, Kohlstedt DL (2022) Diffusion rates of hydrogen defect species associated with site-specific infrared spectral bands in natural olivine. Earth and Planetary Science Letters 581, 117406

2023

Barth A, Plank T, Towbin H (2023) Rates of dehydration in hydrous, high-Fo, magmatic olivines. Geochimica et Cosmochimica Acat 342, 62-71.
Jollands MC (2023) Diffusion of Hydroxylated Si Vacancies in Olivine, and Its Relevance to Si Diffusion. Geochemistry, Geohysics, Geosystems 24, e2022GC010731.

2024

Zhu CY, Chen H, Hao YT, Xia Q (2024) The Effects of Partial Melting and Metasomatism on Peridotite Water Contents: Insights from Shuangliao Volcano Group, Northeast China. Journal of Petrology 65, egae003. https://doi.org/10.1093/petrology/egae003