Hydrogen in Earth's Mantle

• McGetchin TR, Silver LT, Chodos AA (1970) Titanoclinohumite: A Possible Mineralogical Site for Water in the Upper Mantle. Journal of Geophysicsl Research 75, 255-259
• Martin RF, Donnay G (1972) Hydroxyl in the Mantle. American Mineralogist 57, 554-470.

• Ackermann L, Cemic L, Langer K (1983) Hydrogarnet substitution in pyrope: a possible location for "water" in the mantle. Earth and Planetetary Science Letters 52, 208-214.
• Aines RD, Rossman GR (1984) Water content of mantle garnets. Geology 12, 720-723.

• Rossman GR, Smyth JR (1990) Hydroxyl contents of accessory minerals in mantle eclogites and related rocks. American Mineralogist 75, 765-780.
• Bell DR, Rossman GR (1992) Water in earth's mantle; the role of nominally anhydrous minerals. Science 255, 1391-1395.
• Bell DR, Rossman GR (1992)  The distrubution of hydroxyl in garnets from the subcontinental mantle of southern Africa. Contributions to Mineralogy and Petrology 111, 1616-178.  
  
• Thompson AB (1992) Water in Earth's upper mantle. Nature 358, 295-302
• Kurosawa M, Yurimoto H, Matsumoto K, Sueno S (1993) Water in Earth’s mantle: hydrogen analysis of mantle olivine, pyroxenes and garnet using the SIMS. Proc Lunar Planet Sci Conf 24th, 839–840.
• Inoue T, Yurimote H, Kudoh Y (1995) Hydrous modified spinel, Mg_1.75SiH_0.5O₄ - A new water reservoir in the mantle trnsition region. Geophysical research leters 22, 117-120.
  
• Sobolev AV, Chaussidon M (1996) H₂O concentrations in primary melts from supra-subductin zones and mid-ocean ridges: implications for H₂O storate and recycling in the mantle. Earth and Planetary Science Letters 137, 45-55. 
  
• Beran A (1998) Contribution of IR spectroscopy to the problem of water in the Earth's mantle. Microscopic Properties and  Processes in Minerals  Book Series: ‏ NATO Advanced Science Institutes Serics C, Mathematical and Physica Sciences: ‏ 543, ‏ 523-538
  

• Bolfan-Casanova N, Keppler H, Rubie DC (2000) Water partitioning between nominally anhydrous minerals in the MgO-SiO₂-H₂O system up to 24 GPa: implications for the distribution of water in the Earth's mantle. Earth and Planetary Science Letters 182, 209-221.  
• Ingrin J, Skogby H (2000) Hydrogen in nominally anhydrous upper-mantle minerals: concentration levels and implications. European Journal of Mineralogy 12, 543-570.
• Xia QK, Chen DG, Wu YB (2000) An important carrier for HPUHP metamorphic fluids: nominally anhydrous minerals. Geol. Rev. 46, 461–465 (in Chinese with English abstract).  
  
• Ohtani E, Toma M, Litasov K, Kubo T, Suzuki A (2001). Stability of dense hydrous magnesium silicate phases and water storage capacity in the transition zone and lower mantle. Physics of the Earth and Planetary Interiors 124, 105–117.
  
• Murakami M, Hirose K, Yurimoto H, Nakashima S, Takafuji N (2002) Water in Earth's lower mantle.  Science 295, 1885-1887. 
  
• Smyth JR, Frost DJ (2002) The effect of water on the 410-km discontinuity: An experimental study. Geophysical Research Letters 29,  014418.
• Bolfan-Casanova N, Keppler H, Rubie DC (2003) Water partitioning at 660 km depth and evidence for very low water solubilituy in magnesium silicate perovskite. - Geophysical Research Letters 30, 1905 017182.
  
• Litasov KD, Ohtani E, Langenhorst F, Yurimoto H, Kubo T, Kondo T (2003) Water solubility in Mg-perovskites and water storage capacity in the lower mantle. Earth Planet Science Letters 211,189–203.

• Bolfan-Casanova N (2005) Water in Eaerth's mantle. Mineralogical Magazine 69,  229-257.
• Bolfan-Casanova N, McCammon C, Mackwell SJ (2005) Water in Transition Zone and Lower Mantle Minerals. In: Earth's Deep Water Cycle, Volume 168 - AGU Geophysicsl Monograph Series, Jacobsen SD and Van De Lee S eds., p 57-68.
• Haung X, Xu Y, Karato SI (2005) Water content in the transition zone from electrical conductivity of wadsleyite and ringwoodite. Nature 434, 746-749
• Hirschmann MM, Aubaud C, Withers AC (2005) Storage capacity of H₂O in nominally anhydrous minerals in the upper mantle. Earth and Planetary Science Letters 236, 167–181.
  
• Ohtani E, Hirao N, Kondo T, Ito M, Kikegawa T (2005) Iron-water reaction at high pressure and temperature, and hydrogen transport into the core. Physics and Chemistry of Minerals 32, 77–82.
• Smyth JR, Holl CM, Langenhorst F, Laustsen JMS, Rossman GR, Kleppe A, McCammon CA, Kawamoto T, van Aken PA (2005) Crystal chemistry of wadsleyite II and water in the Earth’s interior. Physics and Chemistry of Minerals 31, 691-705
• Bolfan-Casanova N, McCammon C, Mackwell SJ (2006) Water in transition zone and lower mantle minerals. in: Earth's Deep Water Cycle; Ed: Jacobsen Sd and van der Lee S. American Geophysical Union
• Katayama I, Nakashima S, Yurimoto H (2006) Water content in natural eclogite and implication for water transport into the deep upper mantle. Lithos 86, 245-259
  
• Smith JR, Jacobsen SD (2006) Nominally Anhydrous MInerals and Earth's Deep Water Cycle. In: Earth's Deep Water Cycle, Volume 168 - AGU Geophysicsal Monograph Series, Jacobsen SD and Van De Lee S eds., p 1-11
• Wang D, Li H, Yi L, Shi B (2008) The electrical conductivity of upper-mantle rocks: water content in the upper mantle. Physics and Chemistry of Minerals 35, 157- 162

• Peslier AH (2010) A review of water contents of nominally anhydrous natural minerals in the mantles of Earth, Mars and the Moon. Journal of Volcanology and Geothermal Research 197, 239-258 2011
• Karato Si (2011). Water distribution across the mantle transition zone and its implications for global material circulation. Earth and Planetary Science Letters 301, 413–423.
• Kovacs I, Green DH, Rosenthal A, Hermann J, O'Neill HSC, Hibberson WO, Udvardi B (2012) An Experimental Study of Water in Nominally Anhydrous Minerals in the Upper Mantle near the Water-saturated Solidus. Journal of Petrology 53, 2067-2093.
• Mrosko M, Lenz S, McCammon CA, Taran M, Wirth R, KoCh-Müller M (2013) Hydrogen incorporation and the oxidation state of iron in ringwoodite: A spectroscopic study. American Mineralogist 98, 629–636.
• SeamanSJ, Williams ML, Jercinovic MJ, Koteas GC, Brown LB (2013) Water in nominally anhydrous minerals: Implications for partial melting and strain localization in the lower crust Geology 41, 1051-1054
• Doucet LS, Peslier AH, Ionov DA, Brandon AD, Golovin AV, Goncharov AG, Ashchepkov IV (2014) High water contents in the Siberian cratonic mantle linked to metasomatism: An FTIR study of Udachnaya peridotite xenoliths. Geochimoca et Cosmochimica Acta 137, 159-187,
• Luth RW (2014) Volatiles in Earth;s mantle.Treatise on Gecchemisty chapter 3.9, pp 355-389.
• Xu Z. Zheng F, Zhao ZF, Gong B (2014) The hydrous properties of subcontinental lithospheric mantle: Constraints from water content and hydrogen isotope composition of phenocrysts from Cenozoic continental basalt in North China. Geochimica et Cosmochimca Acta 143, p285-302

• Ohtani E. (2015). Hydrous minerals and the storage of water in the deep mantle. Chemical Geology 418, 6–15
• Merli M Bonadiman C, Diella V, Pavese A (2016). Lower mantle hydrogen partitioning between periclase and perovskite: A quantum chemical modelling. Geochimica et Cosmochimica Acta 173, 304–318.
• Nestola F, Smyth JR (2016) Diamonds and water in the deep Earth: a new scenario. International Geology Review 58, 263-276.
  
• Palot M, Jacobsen SD, Townsend JP, Nestola F, Marquardt K, Miyajima N, Harris JW, Stachel T, McCammon CA, Pearson DG (2016) Evidence for H2O-bearing fluids in the lower mantle from diamond inclusion. Lithos 265, 237-243.
• Babushkina MS, Ugolkov VL, Marin YB, Nikitina LP, Goncharov AG (2018) Hydrogen and Carbon Groups in the Structures of Rock-Forming Minerals of Rocks of the Lithospheric Mantle: FTIR and STA plus QMS Data. Docklady Earth Sciences 479, 456-459.
  
• Kaminsky FV (2018). Water in the Earth's lower mantle. Geochemistry International 56, 1117–1134.
  
• Marshall EW, Lassiter JC, Barnes JD (2018) On the (mis)behavior of water in the mantle: Controls on nominally anhydrous mineral water content in mantle peridotites. Earth and Planetary Science Letters 499, 219-229.
  
• Muir JM, Brodholt JP (2018). Water distribution in the lower mantle: Implications for hydrolytic weakening. Earth and Planetary Science Letters 484, 363–369.
•  Li P, Scott JM, Liu J, Xia QK (2018) Lateral H₂O variation in the Zealandia lithospheric mantle controls orogen width. Earth and Planetary Science Letters 502, 200-209.