H in OrthoPyroxenes

Updated 12-Oct-2020 by GR Rossman

1984 

• Aines RD, Rossman GR (1984) Water in minerals? A peak in the infrared. Journal of Geophysical Research 89, 4059-4072

1985

• Beran A, Zemann J (1986) The pleochroism of a gem-quality enstatite in the region of the OH stretching frequency, with a stereochemical interpretation. Tscherm Min Petr Mitt 35, 19-25

1989 

• Skogby H, Rossman, GR (1989) OH-in pyroxene: an experimental study of incorporation mechanisms and  stability. American Mineralogist 74, 1059–1069.
• Skogby H, Bell DR, Rossman GR (1990) Hydroxide in pyroxenes: variations in the natural environment. American Mineralogist 75, 764-774.

1992 

• Bell DR, Rossman GR (1992) Water in the Earth’s mantle: the role of nominally anhydrous minerals. Science 255, 1391-1397

1995

• Bell DR, Ihinger PD, Rossman GR (1995) Quantitative analysis of trace OH in garnet and pyroxenes. American Mineralogist 80, 465-474,
• Dobson PF, Skogby H, Rossman GR (1995) Water in boninite glass and coexisting orthopyroxene: Concentration and partitioning. Contributions to Mineralogy and Petrology, 118, 414– 419. 

1998

• Kohn SC (1998) 1H MAS NMR studies of water solubilities and dissolution mechanisms in olivine, clinopyroxene and orthopyroxene. Mineralogical Magazine 62, 799-800.

2000

• Keppler H, Rauch M (2000) Water solubility in nominally anhydrous minerals measured by FTIR and 1H MAS NMR: the effect of sample preparation, Physics and Chemistry of Minerals  27, 371-276.

2002 

• Peslier AH, Luhr JF, Post J (2002) Low water contents in pyroxenes from spinel-peridotites of the oxidized, sub-arc mantle wedge. Earth and Planetary Science Letters 201, 69-86.
• Rauch M, Keppler H (2002) Water solubility in orthopyroxene. Contributions to Mineralogy and Petrology 143, 525–536.
• Stalder R, Skogby H. (2002) Hydrogen incorporation in enstatite, European Journal of Mineralogy 14, 1139-1144.

2003

• Panero W, Benedetti L, Jeanloz R (2003) Transport of water into the lower mantle: role of stishovite. J Geophy Res 108(B1). DOI 10.1029/2002JB002053
• Stalder R, Skogby H (2003) Hydrogen diffusion in natural and synthetic orthopyroxene. Phys Chem Minerals 30, 12-19.

2004 

• Bell DR, Rossman GR, Moore RO (2004) Abundance and partitioning of OH in a high-pressure magmatic system: Megacrysts from the Monastery kimberlite, South Africa. Journal of Petrology 11, 1539-1564
• Mierdel K, Keppler H (2004) The temperature dependence of water solubility in enstatite. Contributions to Mineralogy and Petrology 148, 305–311.
• Stalder R (2004) Influence of Fe, Cr and Al on hydrogen in-corporation in orthopyroxene. European Journal of Mineralogy 16, 703–711.

2005 

• Stalder R, Klemme S, Ludwig T, Skkogby H (2005) Hydrogen incorporation in orthopyroxene: interaction of different trivalent cations. Contributions to Mineralogy and Petrology pxxx

2006 

• Skogby H (2006) Water in natural mantle minerals I: pyroxenes. In: Keppler H & Smyth JR (eds) Water in Nominally Anhydrous Minerals. Chantilly, VA: Mineralogical Society of America, pp. 155–167.
• Stalder R, Behrens H (2006) D/H exchange in pure and Cr-doped enstatite: implications for hydrogen diffusivity. Physics and Chemistry of Minerals 33, 601-611.
• Xiaozhi Y, Zia Q, Deloule E, Hao Y (2006) Water in the lower continental crust: a case study from the North China Craton. Poster presentation

2007 

• Smyth JR, Mierdel K, Kekppler H, Langenhorst F, Dubrovinsky L, Nestola F (2007) Crystal chemistry of hydration in aluminous orthopyroxene American Mineralogist 92, 973-976.

2008 

• Li ZXA, Lee CTA, Peslier AH, Lenardic A, Mackwell SJ (2008) Water contents in mantle xenoliths from the Colorado Plateau and vicinity: Implications for the mantle rheology and hydration-induced thinning of continental lithosphere, Journal of Geophysical Research - SolidEarth 113 doi:10.1029/2007JB005540
• Stalder R, Kronz A, Simon K (2008): Hydrogen incorporation in enstatite in the system MgO-SiO₂-H₂O-NaCl. Contributions to Mineralogy and Petrology 156, 653-659.
• Yang X, Xia Q, Deloule E, Dalllai L, Fan Q, Feng M (2008) Water in minerals of the continental lithospheric mantle and overlying lower crust: A comparative study of peridotite and granulite xenoliths from the North China Craton. Chemical Geology 256, 33-45.   

2009

• Bureau H, Raepsaet C, Khodja H, Carraro A, Aubaud C (2009) Determination of hydrogen content in geological samples using elastic recoil detection analysis (ERDA). Geochimica et Cosmochimica Acta 73, 3311–3322.
• Gose J, Schmädicke, E, Beran A (2009) Water in enstatite from Mid-Altantic Ridge peridotite: evidence for the water content of suboceanic mantle? Geology 37, 543–546.
• Purwin H, Stalder R, Skogby H (2009) Hydrogen incorporation in Fe- and Na-doped diopsides. European Journal of Mineralogy 21, 691-704. 
• Tenner TJ, Hirschmann MM, Withers AC, Hervig RL (2009) Hydrogen partitioning between nominally anhydrous upper mantle minerals andmelt between 3 and 5 GPa and applications to hydrous peridotite partial melting. Chemical Geology  262, 42-56.

2010

• Begaudeau K, Morizet Y, Mercier J (2010) Water contents and OH speciation in pyroxenes - American Geophysical Union Annual Meeting 2010, Abstract AN: V23E-04
• Prechtel F, Stalder R (2010) FTIR spectroscopy with a focal plane array detector: A novel tool to monitor the spatial OH-defect distribution in single crystals applied to synthetic enstatite. American Mineralogist 95, 888–891.  
• Xia QK, Hao Y, Li IP, Deloule E, Coltorti M, Dallai L, Yang X, Feng M (2010) Low water content of the Cenozoic lithospheric mantlebeneath the eastern part of the North China Craton.  Journal of Geophysical Research 114, B07207
• Zhang BM, Zhang XL, Di JR, Ye DL (2010) Structural OH and hydrogen and oxygen isotope of pyroxenes from upper mantle in Fujitian, Hainan, China. Dizhi Keji Qingbao 39, 107. in Chinese.

2011

• Gose J, Schmädicke E, Stalder R (2011) Water in mantle orthopyroxene – no visible change in defect water during serpentinization. European Journal of Mineralogy 23, 529-536.
• Prechtel F, Stalder R (2011): The potential use of OH-defects in enstatite as geobarometer. Contributions to Mineralogy and Petrology 162/3, 615 - 623.
• Schmadicke E, Gose J, Will TM (2011) Heterogeneous mantle underneath the North Atlantic: Evidence from water in orthopyroxene, mineral composition and equilibrium conditions of spinel peridotite from different locationa at the Mid-Alantic Ridge. Lithos 125, 308-320
• Sundvall R, Stalder R (2011) Water in upper mantle pyroxene megacrysts and xenocrysts: A survey study. American Mineralogist 96, 1215-1227.
• Wang R, Zhang BM (2011) Water in peridotite xenoliths from Niutoushan, Longhai, Fujan. Diqiu Kexue 36, 635-642. in Chinese.

2012

• Balan E, Blanchard M, Yi H, Ingrin J (2012) Theoretical study of OH-defects in pure enstatite. Physics and Chemistry of Minerals. DOI 10.1007/s00269-012-0544-6
• Kovacs I, Green HW, Rosen thal A, Hermann J, O'Neill HSC, Hibberson WO, Udvardi B (2012) An experimental study water in nominally anhydrous minerals in the upper mantle near water-saturated solidus. Journal of Petrolroloty 53, 2067-2093.
• Prechtel F, Stalder R (2012) OH-defects in Al- and Cr-doped synthetic enstatites and defect geobarometry on natural orthopyroxenes from the Earth’s mantle. European Journal of Mineralogy 24, 471-481.
• Karimova, A; Stalder, R (2013): OH in diopside and enstatite at 6 GPa in the system CaO-MgO-SiO₂-H₂O. European Journal of Mineralogy 25, 299-305. 
• Schlechter E, Stalder R, Behrens H (2012) Electrical conductivity of H-bearing orthopyroxene single-crystals measured with impedance spectroscopy. Physics and Chemistry of Minerals 39, 531 - 541.
• Stalder R, Prechtel F, Ludwig T (2012) No site-specific infrared absorption coefficients for OH-defects in pure enstatite. European Journal of Mineralogy 24, 465-470. 
• Yang Y, Xia Q, Feng M, Liu S (2012) OH in natural orthopyroxene: an in situ FTIR investigation at varying temperatures. Physics and Chemistry ofMinerals 39, 413–418.

2013 

• Balan E, Blanchard M, Yi H, Ingrin J (2013) Theoretical study of OH-defects in pure enstatite. Physand Chemistry of Minerals, 40, 41-50.
• BoaHua Z, Matsuzaki T, XioPing W (2013) Water solubility in orthopyroxene: Dependence on temperature and Al content. Chinese Science Bulletin 58, 3895-3902.
• Hao Y,Xia Q, Liu S, Gu X, Feng M, Zhang Y (2013) Recognizing juvenile and relict lithospheric mantle beneath the North China Craton: Combined analysis of H2O, major and trace elements and Sr–Nd isotope compositions of clinopyroxenes. Lithos 149, 136-145.
• Karimova, A; Stalder, R (2013): OH in diopside and enstatite at 6 GPa in the system CaO-MgO-SiO₂-H₂O. In: European Journal of Mineralogy 25/3, pp. 299 - 305.
• Mosenfelder JD, Rossman GR (2013) Analysis of hydrogen and fluorine in pyroxenes by SIMS and FTIR: Part I. Orthopyroxene. American Mineralogist 98, 1026-1041.
• Stalder R, Prechtel F, Ludwig T (2012) No site-specific infrared absorption coefficients for OH-defects in pure enstatite. European Journal of Mineralogy 24/3, 465 - 470.
• Warren JM, Hauri EH (2014). Pyroxenes as tracers of mantle water variations. Journal of Geophysical Research: Solid Earth 119, 1851– 1881. 
• Xia Q, Hao Y, Liu S, Gu X, Feng M (2013) Water contents of the Cenozoic lithospheric mantle beneath the western part of the North China Craton: Peridotite xenolith constraints. Gondwana Research 23, 108-118.

2014

• Hao Y, Xia Q, Li Q, Chen H, Feng M (2014) Partial melting control of water contents in the Cenozoic lithospheric mantle of the Cathaysia block of South China. Chemical Geology 380, 7-19.
• Sakurai M, Sakuma H, Tsujino N, Takahashi E, Kawamura K (2014) Determination of Hydrogen Atoms Position in Enstatite by IR Spectra. Journal of Computer Chemistry, Japan 13, 169-170. (in Japanese).  
• Wang Q, Bagdassarov N, Xia Q, Zhu B (2014) Water contents and electrical conductivity of peridotite xenoliths from the North China Craton: Implications for water distribution in the upper mantle. Lithos 189, 105-126.

2015 

• Hesse KR, Gose J, Stalder R, Schmadicke E (2015) Water in orthopyroxene from abyssal spinel peridotites of the East Pacific Rise (ODP Leg 147: Hess Deep). Lithos 232, 23-34.  
• Li P, Xia Q, Deloule E, Chen H, Gu X, Feng M (2015) Temporal variation of H₂O content in the lithospheric mantle beneath the eastern North China Craton: Implications for the destruction of cratons. Gondwana Research 28, 276-287.
• Stalder, R; Karimova, A; Konzett, J (2015): OH-defects in multiple-doped orthoenstatite at 4–8 GPa: filling the gap between pure and natural systems.
  In: Contributions to Mineralogy and Petrology 169, Art. Nr. 38. 

2016

• Hao Y, Xia Q, Jia Z, Zhao Q, Li P, Feng M, Liu S (2016) Regional heterogeneity in the water content of the Cenozoic lithospheric mantle of Eastern China. Journal of Geophysical Research: Solid Earth 121, 517-537.
• Weis F, Stalder R, Skogby H (2016) Experimental hydration of natural volcanic clinopyroxene phenocrysts under hydrothermal pressures (0.5-3 kbar). American Mineralogist 101, 2233-2247.
• Frigo C, Stalder R, Hauzenberger C (2016): OH defects in quartz in granitic systems doped with spodumene, tourmaline and/or apatite: experimental investigations at 5–20 kbar. Physics And Chemistry Of Minerals 43, 717,729. 

2017

• Stalder R, Potrafke A,; Billström K, Skogby H, Meinhold G, Gögele C, Berberich T (2017): OH-defects in quartz as monitor for igneous, metamorphic and sedimentary processes. American Mineralogist 102/9, 1832-1842.  
• Tian Z, Xia Q, Ingrin J, Hao Y, Christophe D (2017) Water concentration profiles in natural mantle orthopyroxenes: A geochronometer for long annealing of xenoliths within magma. Geology 45, 87-90.  
  

2018

• Schmädicke, Gose J, Stalder R (2018) Water in Abyssal Peridotite: Why Are Melt-Depleted Rocks so Water Rich? Geochemistry Geophysics Geosystems 13, 1824-1843.
• Hao YT, Li P, Coltorti M, Xia QK (2018) Variations in the H₂O Content and H₂O/Ce Ratio of Mantle Pyroxenites: Implications for Enriched Components in the Mantle. Journal of Geophysical Research: Solid Earth 123, on-line
•  Li P, Scott JM, Liu J, Xia Q (2018)  Lateral H₂O variation in the Zealandia lithospheric mantle controls orogen width. Earth and Planetary Science Letters 502, 200–209.

2019

•   Tollan P, Hermann J (2019) Arc magmas oxidized by water dissociation and hydrogen incorporation in orthopyroxene. Nature Geoscience 12, 667-671.