H in Pyroxenes

H in Pyroxenes

Updated 9-Apr-2025 by GR Rossman

1970s

Mikenda W, Steinböck S (1996) Stretching frequency vs. bond distance correlation of hydrogen bonds in solid hydrates: a generalized correlation function. J Mol Struct 384:159–163
Beran A (1976) Messung des Ultrarot-Pleochroismus von Mineralen. XIV. Der Pleochroismus der OH-Streckfrequenz in Diopsid. Tschermaks Mineralogische und Petrographische Mitteilungen 23, 79-85.

1980s

Aines RD, Rossman GR (1984) Water in minerals? A peak in the infrared. Journal of Geophysical Research 89, 4059-4072
Beran A, Zemann J (1986) The pleochroism of a gem-quality enstatite in the region of the OH stretching frequency, with a stereochemical interpretation. Tscherm Min Petr Mitt 35, 19-25.
Ingrin J, Latrous K, Doukhan JC, Doukhan N (1989) Water in diopside: an electron microscopy and infrared spectroscopy study. European Journal of Mineralogy 1, 327-341.
Skogby H, Rossman GR (1989) Hydroxide ion in pyroxene: An experimental study of incorporation mechanisms and stability. American Mineralogist 74, 1059-1069.

1990s

Skogby H, Bell DR, Rossman GR (1990) Hydroxide in pyroxene: variations in the natural environment. American Mineralogist 75, 764-774.
Smyth JR, Bell DR, Rossman GR (1991) Incorporation of hydroxyl in upper-mantle clinopyroxenes. Nature 351:732–735
Bell DR, Rossman GR (1992) Water in Earth’s mantle the role of nominally anhydrous minerals, Science 255, 1391-1397.
Skogby H (1994) OH incorporation in synthetic clinopyroxene, Am. Mineral. 79, 240-249.
Zhang LM (1984) The incorporation mechanism of strutural OH in abyssal clinopyroxene. Chinese Science Bulletin 39, 1912-1915.
Bell DR, Rossman GR (1992) Water in the Earth’s mantle: the role of nominally anhydrous minerals. Science 255, 1391-1397
Beran A, Langer K, Andrut M (1993) Single Crystal Infrared Spectra in the Range of OH Fundamentals of Paragenetic Garnet, Omphacite and Kyanite in an Eklogitic Mantle Xenolith. Mineralogy and Petrology 48, 257-268.
Kurosawa M, Yurimoto H, Matsumoto K, Sueno S (1993) Water in Earth’s mantle: hydrogen analysis of mantle olivine, pyroxenes and garnet using the SIMS. Proc Lunar Planet Sci Conf 24th, 839–840
Bell DR, Ihinger PD, Rossman GR (1995) Quantitative analysis of hydroxyl in garnet and pyroxene. American Mineralogist 80, 465-474.
Dobson PF, Skogby H, Rossman GR (1995) Water in boninite glass and coexisting orthopyroxene: Concentration and partitioning. Contributions to Mineralogy and Petrology, 118, 414– 419.
Ingrin J, Hercule S, Charton T (1995) Diffusion of hydrogen in diopside: Results of dehydration experiments. Journal of Geophysical Research, 100, 15489–15499.
Kohn SC (1996) Solubility of H₂O in nominally anhydrous mantle minerals using 1-H MAS NMR. American Mineralogist 81, 1523-1526.
Snyder GA, Taylor LA, Jerde EA, Clayton RN, Mayeda TK, Deines P, Rossman GR, Sobolev NV (1995) Hydroxyl contents, and carbon and oxygen isotopic compositions of diamondiferous eclogites from the Udachnaya Kimberlite pipe, Yakutia, Siberia. American Mineralogist 80, 799-809.
Dyar MD, Martin SV, Mackwell SJ, Carpenterr S, Grant CA, McGiuire AV (1996) Chemistry of Fe³⁺, H⁺ and D/H in mantle-derived autite from Dish Hill: Implications for alteration during transport. Mineral Spectroscopy: A tribute to Roger G. Burns. THe Geochemical Society Special Publication No. 5. pp 289-304.
Sweeney RJ, Prozesky VM, Spinghorn KA (1997) Use of the elastic recoil detection analysis (ERDA) microbeam technique for the quantitative determination of hydrogen in materials and hydrogen partitioning
between olivine and melt at high pressures. Geochimicaet Cosmochimica Acta 61, 101-113.
Guo L, Lin X, Xie M, Feng J, Wu S (1998) Water in mantle-derived xenoliths from the Hannuoba basalt, China. Dizhi Xuebao 72, 138-143.
Kohn SC (1998) ¹H MAS NMR studies of water solubilities and dissolution mechanisms in olivine, clinopyroxene and orthopyroxene. Mineralogical Magazine 62, 799-800.

2000-2004

Bolfan-Casanova N, Keppler H, Rubie DC (2000) Water partitioning between nominally anhydrous minerals in
the MgO-SiO2-H2O system up to 24 GPa: implications for the distribution of water in the Earth's mantle. Earth and Planetary Science Letters 182, 209-221.
Freund F, Dickinson JT, Cash M (2002) Hydrogen in Rocks: An Energy Source for Deep Microbial Communities. Astrobiology 2, 83- 92
Ingrin J, Skogby H (2000) Hydrogen in nominally anhydrous upper-mantle minerals: concentration levels and implications. European Journal of Mineralogy 12, 543-570.
Keppler H, Rauch M (2000) Water solubility in nominally anhydrous minerals measured by FTIR and 1H MAS NMR: the effect of sample preparation, Physics and Chemistry of Minerals 27, 371-276.
Locke, D.R., Holloway, J.R., and Hervig, R., 2000, Experimental determination of H₂O solubility in mantle clinopyroxene at 5 and 7.5 GPa: Eos (Transactions, American Geophysical Union) 81, V52–D05.
Woods SC, Mackwell S, Dyar D (2000) Hydrogen in diopside: difusion profiles. American Mineralogist 85, 480–487.
Xia Q, Chen D, Carpenter S, Zhi X, Wang R, Cheng H (2000) Hydrogen diffusion in clinopyroxene: dehydration experiments. Science in China Series D: Eaerth Sciences 43, 561-568.
Johnson EA, Rossman GR, Dyar MD, Valley JW (2002) Correlation between OH concentration and oxygen isotope diffusion rate in diopsides from the Adirondack Mountains, New York. American Mineralogist 87. 899–908.
Peslier AH, Luhr JF, Post J (2002) Low water contents in pyroxenes from spinel-peridotites of the oxidized, sub-arc mantle wedge. Earth and Planetary Science Letters 201, 69-86.
Rauch M, Keppler H (2002) Water solubility in orthopyroxene. Contributions to Mineralogy and Petrology 143, 525–536.
Smyth JR, Frost DJ (2002) The effect of water on the 410-km discontinuity: An experimental study. Geophysical Research Letters 29, 1485-014418
Stalder R, Skogby H. (2002) Hydrogen incorporation in enstatite, European Journal of Mineralogy 14, 1139-1144.
Andrut M, Brandstätter F, Beran A (2003) Trace hydrogen zoning in diopside. Mineralogy and Petrology 78, 231–241.
Beran A, Libowitzky E (2003) IR Spectroscopic Characterization of OH Defects in Mineral Phases. Phase Transitions 76, 1-15.
Katayama, I, Nakashima S (2003) Hydroxyl in clinopyroxene from the deep subducted crust: Evidence for H₂O transport into the mantle. American Mineralogist 88, 229-234.
Koga K, Hauri E, Hirschmann M, Bell D (2003) Hydrogen concentration analyses using SIMS and FTIR: Comparison and calibration for nominally anhydrous minerals. Geochemistry Geophysics Geosystems 4, 1019
Panero W, Benedetti L, Jeanloz R (2003) Transport of water into the lower mantle: role of stishovite. J Geophy Res 108(B1). DOI 10.1029/2002JB002053
Stalder R, Skogby H (2003) Hydrogen diffusion in natural and synthetic orthopyroxene. Phys Chem Minerals 30, 12-19.
Aubaud C, Hauri E, Hirschmann MM (2004) Hydrogen partition coefficients between nominally anhydrous minerals and basaltic melts. Geophysical Research Letters 31, L20611.
Bell DR, Rossman GR, Moore RO (2004) Abundance and Partitioning of OH in a Highpressure Magmatic System: Megacrysts from the Monastery Kimberlite, South Africa. Journal of Petrology 45, 1539-1564.
Bromiley GD, Keppler H (2004) An experimental investigation of hydroxyl solubility in jadeite and Na-rich clinopyroxenes. Contributions to Mineraogy and Petrology 147, 189-200.
Bromiley GD, Keppler H, McCammon C, Bromiley FA, Jacobsen SD (2004) Hydrogen solubility and speciation in natural, gem-quality chromian diopside. American Mineralogist 89, 941–949.
Bromiley GD, Keppler H, McCammon C, Bromiley FA, Jacobsen SD (2004) Erratum: Hydrogen solubility and speciation in natural, gem-quality chromian diopside. American Mineralogist 89, 1352.
Bromiley GD & Keppler H (2004) An experimental investigation of hydroxyl solubility in jadeite and Na-rich clinopyroxenes. Contributions to Mineralogy and Petrology 147, 189–200.
Koch-Müller M, Matsyuk SS, Wirth R (2004) Hydroxyl in omphacites and omphacitic clinopyroxenes of upper mantle to lower crustal origin beneath the Siberian platform. American Mineralogist 89, 921–931.
Libowitzky E, Beran A (2004) IR spectroscopic characterisation of hydrous species in minerals. In: Beran A, Libowitzky E (eds) Spectroscopic methods in mineralogy. EMU Notes Mineral 6, EötvösUniv Press, Budapest, pp 227–279
Mierdel K, Keppler H (2004) The temperature dependence of water solubility in enstatite. Contributions to Mineralogy and Petrology 148, 305–311.
Sheng YM, Xia QK, Wang RC, Chen XM, Yu XM, Yang XZ (2004) Water in clinopyroxeses from eclogites of Bixiling and Huangzheng, Dabieshan and geodynamic implications. Acta Petrologica Sinica 20:1133-1140.
Stalder R (2004) Influence of Fe, Cr and Al on hydrogen in-corporation in orthopyroxene. European Journal of Mineralogy 16, 703–711.
Su W, Ji Z, Ye K, You Z, Liu J, Yu J, Cong B (2004) Distribution of hydrous components in jadeite of the Dabie Mountains. Earth andPlanetetary Science Letters 222, 85–100.

2005-2006

Guilhaumou N, Sautter V, Dumas P (2005) Synchrotron FTIR microanalysis of volatiles in melt inclusions and exsolved particles in ultramafic deep-seated garnets. Chemical Geology 223, 82-92.
Hier-Majumder S, Mei S, Kohlstedt DL (2005) Water weakening of clinopyroxenenite in diffusion creep. Journal of Geophysical Research 110, B07406.
Stalder R, Klemme S, Ludwig T, Skkogby H (2005) Hydrogen incorporation in orthopyroxene: interaction of different trivalent cations. Contributions to Mineralogy and Petrology pxxx
Wegden M, Kristiansson P, Skogby H, Auzelyte V, Elfman M, Malmqvist KG, Nilsson C, Pallon J, Shariff A (2005) Hydrogen depth profiling by p–p scattering in nominally anhydrous minerals. Nuclear Instruments and Methods in Physics Research B 231, 524–529.
Demouchy S, Jacobsen SD, Gaillard F, Stern CR (2006) Rapid magma ascent recorded by water diffusion profiles in mantle olivine. Geology 34, 429-432.
Filip J, Novák M, Beran A, Zbořil R (2006) Crystal chemistry and OH defect concentrations in spodumene from different granitic pegmatites. Physics and Chemistry of Minerals 32, 733-346.
Grant KJ, Kohn SC, Brooker RA (2006) Solubility and partitioning of water in synthetic forsterite and enstatite in the system MgO–SiO2–H2O±Al2O3. Contributions to Mineralogy and Petrology. DOI 10.1007/s00410-006-0082-7
Katayama I, Nakashima S, Yurimoto H (2006) Water content in natural eclogite and implication for water transport into the deep upper mantle. Lithos 86, 245-259.
Kikuchi M, Ogasawara Y (2006) Hydroxyl in diopside of diamond-free dolomitic marble from the Kokchetav Massif, Kazakhstan: Geological Society of America Special Paper 403, 139–145.
Libowitzky E, Beran A (2006) The structure of hydrous species in nominally anhydrous minerals: information from polarized IR spectroscopy. In: Keppler H, Smyth JR (eds) Water in nominally anhydrous minerals. Rev Mineral Geochem 62, Minerogical Society of America, 29–52.
Skogby H (2006) Water in natural mantle minerals I: pyroxenes. In: Keppler H & Smyth JR (eds) Water in Nominally Anhydrous Minerals. Chantilly, VA: Mineralogical Society of America, pp. 155–167.
Stalder R, Behrens H (2006) D/H exchange in pure and Cr-doped enstatite: implications for hydrogen diffusivity. Physics and Chemistry of Minerals 33, 601-611
Xiaozhi Y, Xia Q, Deloule E, Hao Y (2006) Water in the lower continental crust: a case study from the North China Craton. Poster presentation
Xia Q, Yang X, Deloule E, Sheng Y, Hao Y (2006) Water in the lower crustal granulite xenoliths from Nushan, eastern China. Journal of Geophysical Research 111, B11202.

2007-2009

Aubaud C. Withers AC, Hirschmann MM, Guan Y, Leshin LA, Mackwell SJ, Bell DR (2007) Intercalibration of FTIR and SIMS for hydrogen measurements in glasses and nominally anhydrous minerals. American Mineralogist 92, 811–828.
Andrut M, Wildner M, Ingrin J, Beran A (2007) Mechanisms of OH defect incorporation in naturally occurring, hydrothermally formed diopside and jadeite. Phys Chem Minerals 34. 543–549.
Chen RX, Zheng YF, Gong B, Zhao ZF, Gao TS, CHen B, Wu YB (2007) Origin of retrograde fluid in ultrahigh-pressure metamorphic rocks: Constraints from mineral hydrogen isotope and water content changes in eclogite–gneisstransitions in the Sulu orogen. Geochimica et Cosmochimica Acta 71, 2299–2325.
Mierdel K, Keppler H, Smyth JR, Langenhorst F (2007) Water solubility in aluminous orthopyroxene and the origin of Earth's asthenosphere. Science 315, 364-368.
Sheng YM, Xia QK, Dallai L, Yang XZ, Hao YT (2007) H₂O contents and D/H ratios of nominally anhydrous minerals from ultrahigh-pressure eclogites of the Dabie orogen, eastern China. Geochimica et Cosmochimica Acta 71, 2079–2103.
Smyth JR, Mierdel K, Kekppler H, Langenhorst F, Dubrovinsky L, Nestola F (2007) Crystal chemistry of hydration in aluminous orthopyroxene American Mineralogist 92, 973-976.
Stalder R, Ludwig T (2007) OH incorporation in synthetic diopside. European Jouornal of Mineraleralogy 19, 373–380.
Konzett J, Libowitzky E, Hejny C, Miller C & Zanetti A (2008) Oriented quartzþcalcic amphibole inclusions in omphacite from the Saualpe and Pohorje Mountain eclogites, Eastern Alps - an assessment of possible formation mechanisms based on IR- and mineral chemical data and water storage in eastern Alpine eclogites. Lithos 106,336–350.
Li ZXA, Lee CTA, Peslier AH, Lenardic A, Mackwell SJ (2008) Water contents in mantle xenoliths from the Colorado Plateau and vicinity: Implications for the mantle rheology and hydration-inducedthinning of continental lithosphere. Journal of Geophysical Reseach 113, B09210.
Stalder R, Kronz A, Simon K (2008): Hydrogen incorporation in enstatite in the system MgO-SiO₂-H₂O-NaCl. Contributions to Mineralogy and Petrology 156, 653-659.
Su W, Zhang M, REdfern SAT, Bromiley GD (2008) Dehydroxylation of omphacite of eclogite from the Dabie-Sulu. Lithos 105, 181-190.
Wade JA, Plank T, Hauri EH, Kelley KA, Roggensack K, Zimmer M (2008) Prediction of magmatic water contents via measurement of H₂O in clinopyroxene phenocrysts. Geology 36:799–802.
Yang X, Xia Q, Deloule E, Dalllai L, Fan Q, Feng M (2008) Water in minerals of the continental lithospheric mantle and overlying lower crust: A comparative study of peridotite and granulite xenoliths from the North China Craton. Chemical Geology 256, 33-45.
Aubuad C, Bureau H, Raepsaet C, Khodja H, WIthers AC, Hirschmann MM, Bell DR (2009) Calibration of the infrared molar absorption coefficients for H in olivine, clinopyroxene and rhyolitic glass by elastic recoil detection analysis. Chemial Geology 262, 78-86.
Bonadiman C, Hao Y, Coltorti M, Dallai L, Faccini B, Huang Y, Xia Q (2009) Water contents of pyroxenes in intraplate lithospheric mantle. European Journal of Mineralogy 21, 637-647.
Bureau H, Raepsaet C, Khodja H, Carraro A, Aubaud C (2009) Determination of hydrogen content in geological samples using elastic recoil detection analysis (ERDA). Geochemica et Cosmochicha Acta 73, 3311-3322.
Gose J, Schmädicke, E, Beran A (2009) Water in enstatite from Mid-Altantic Ridge peridotite: evidence for the water content of suboceanic mantle? Geology 37, 543–546.
Purwin H, Stalder R, Skogby H (2009): Hydrogen incorporation in Fe- und Na-doped diopsides. European Journal of Mineralogy 21,691-704.
Sundvall R, Skogby H, Stalder R (2009) Hydrogen diffusion in synthetic Fe-free diopside. European Journal of Mineralogy 21, 963-970.
Tenner TH, Hirschmann MM, WIthers AC, Hervig RL (2009) Hydrogen partitioning between nominally anhydrous upper mantle minerals and melt between 3 and 5 GPa and applications to hydrous peridotite partial melting. Chemical Geology 262, 42-56.

2010-2012

Begaudeau K, Morizet Y, Mercier J (2010) Water contents and OH speciation in pyroxenes. 2010 AGU Fall Meeting, San Francisco, CA. Abstract V23E-04
Peslier (2010) A review of water contents of nominally anhydrous natural minerals in the mantles of Earth, Mars and the Moon. Journal of Volcanology and Geothermal Research 197, 239-258.
O'Leary JA, Gaetani GA, Hauri EH (2010) The effect of tetrahedral Al³⁺ on the partitioning of water between clinopyroxene and silicate melt. Earth and Planetary Science Letters 297, 111-120.
Peslier AH, Woodland AB, Bell DR, Lazarov M (2010) Olivine water contents in the continental lithosphere and the longevity of cratons. Nature 467, 78–81.
Prechtel F, Stalder R (2010) FTIR spectroscopy with a focal plane array detector: A novel tool to monitor the spatial OH-defect distribution in single crystals applied to synthetic enstatite. American Mineralogist 95, 888–891.
Xia QK, Hao Y, Li P, Deloule E, Coltorti M, Dallai L, Yang X Feng M (2010) Low water content of the Cenozoic lithospheric mantlebeneath the eastern part of the North China Craton. Journal of Geophysical Research 115, B07207.
Yang Y, Xia Q, Feng M, Zhang P (2010) Temperature dependence of IR absorption of OH species in clinopyroxene. American Mineralogist 95,1439–1443.
Zhang BM, Zhang XL, Di JR, Ye DL (2010) Structural OH and hydrogen and oxygen isotope of pyroxenes from upper mantle in Fujitian, Hainan, China. Dizhi Keji Qingbao 39, 107. in Chinese.
Gose J, Schmädicke E, Stalder R (2011) Water in mantle orthopyroxene – no visible change in defect water during serpentinization. European Journal of Mineralogy 23, 529-536.
Prechtel F, Stalder R (2011): The potential use of OH-defects in enstatite as geobarometer. Contributions to Mineralogy and Petrology 162/3, 615 - 623.
Schmadicke E, Gose J, Will TM (2011) Heterogeneous mantle underneath the North Atlantic: Evidence from water in orthopyroxene, mineral composition and equilibrium conditions of spinel peridotite from different locationa at the Mid-Alantic Ridge. Lithos 125, 308-320
Sundvall R, Skogby H (2011) Hydrogen defect saturation in natural pyroxene. Physics and Chemistry of Minerals 38, 335–344.
Sundvall R, Stalder R (2011) Water in upper mantle pyroxene megacrysts and xenocrysts: A survey study. American Mineralogist 96, 1215-1227.
Wang R, Zhang BM (2011) Water in peridotite xenoliths from Niutoushan, Longhai, Fujan. Diqiu Kexue 36, 635-642. in Chinese.
Yang, X.Z., and Keppler, H. (2011) In-situ infrared spectra of OH in olivine to 1100 °C. American Mineralogist, 96, 451–454.
Balan E, Blanchard M, Yi H, Ingrin J (2012) Theoretical study of OH-defects in pure enstatite. Physics and Chemistry of Minerals. DOI 10.1007/s00269-012-0544-6
Baptiste V, Tommasi A, Demouchy S (2012) Deformation and hydration of the lithospheric mantle beneath the Kaapvaal craton, South Africa. Lithos 149, 31-50.
Kovacs I, Green HW, Rosen thal A, Hermann J, O'Neill HSC, Hibberson WO, Udvardi B (2012) An experimental study water in nominally anhydrous minerals in the upper mantle near water-saturated solidus. Journal of Petrolroloty 53, 2067-2093.
Peslier AH, Woodland AB, Bell DR, Lazarov M, Lapen TJ (2012) Metasomatic control of water contents in the Kaapvaal cratonic mantle. Geochimica CosmochimicaActa 97, 213–246.
Prechtel F, Stalder R (2012) OH-defects in Al- and Cr-doped synthetic enstatites and defect geobarometry on natural orthopyroxenes from the Earth’s mantle. European Journal of Mineralogy 24, 471-481.
Stalder R, Prechtel F, Ludwig T (2012) No site-specific infrared absorption coefficients for OH-defects in pure enstatite. European Journal of Mineralogy 24/3, 465 - 470.
Karimova, A; Stalder, R (2013): OH in diopside and enstatite at 6 GPa in the system CaO-MgO-SiO₂-H₂O. European Journal of Mineralogy 25, 299-305.
Schlechter E, Stalder R, Behrens H (2012) Electrical conductivity of H-bearing orthopyroxene single-crystals measured with impedance spectroscopy. Physics and Chemistry of Minerals 39, 531 - 541.
Stalder R, Prechtel F, Ludwig T (2012) No site-specific infrared absorption coefficients for OH-defects in pure enstatite. European Journal of Mineralogy 24, 465-470.
Yang Y, Xia Q, Feng M, Liu S (2012) OH in natural orthopyroxene: an in situ FTIR investigation at varying temperatures. Physics and Chemistry ofMinerals 39, 413–418.

2013-2015

Balan E, Blanchard M, Yi H, Ingrin J (2013) Theoretical study of OH-defects in pure enstatite. Physand Chemistry of Minerals, 40, 41-50.
BoaHua Z, Matsuzaki T, XioPing W (2013) Water solubility in orthopyroxene: Dependence on temperature and Al content. Chinese Science Bulletin 58, 3895-3902.
Hao Y,Xia Q, Liu S, Gu X, Feng M, Zhang Y (2013) Recognizing juvenile and relict lithospheric mantle beneath the North China Craton: Combined analysis of H2O, major and trace elements and Sr–Nd isotope compositions of clinopyroxenes. Lithos 149, 136-145.
Karimova, A; Stalder, R (2013): OH in diopside and enstatite at 6 GPa in the system CaO-MgO-SiO₂-H₂O. In: European Journal of Mineralogy 25/3, pp. 299 - 305.
Mosenfelder JD, Rossman GR (2013) Analysis of hydrogen and fluorine in pyroxenes by SIMS and FTIR: Part I. Orthopyroxene. American Mineralogist 98, 1026-1041.
Mosenfelder J, Rossman GR (2013) Analysis of hydrogen and fluorine in pyroxenes: II. Clinopyroxene. Am Mineral 98:1042–1054
Peltier J (2013) Water in nominally anhydrous minreals from anakhlites and shergottites. 44th Lunar and Planetary Conference, 1130
Warren JM, Hauri EH (2013) Pyroxenes as tracers of mantle water variations. Journal of Geophysical Research 119, 1851-1881.
Xia Q, Hao Y, Liu S, Gu X, Feng M (2013) Water contents of the Cenozoic lithospheric mantle beneath the western part of the North China Craton: Peridotite xenolith constraints. Gondwana Research 23, 108-118.
Xia QK, Liu J, Liu SC, Kovács I, Feng M, Dang L (2013) High water content in Mesozoic primitive basalts of the North China Craton and implications on the destruction of cratonic mantle lithosphere. Earth and Planetary Science Letters 361, 85-97.
Hao Y, Xia Q, Li Q, Chen H, Feng M (2014) Partial melting control of water contents in the Cenozoic lithospheric mantle of the Cathaysia block of South China. Chemical Geology 380, 7-19.
Luth RW (2014) Volatiles in Earth;s mantle.Treatise on Gecchemisty chapter 3.9, pp 355-389.
Sakamaki K, Ogasawara Y (2014) Hydroxyl in clinopyroxene and titanite in a UHP diamond-free garnet-clinopyroxene rock from the Kokchetav Massif, northern Kazakhstan. International Geology Review Rev 56, 133-149.
Sakurai M, Sakuma H, Tsujino N, Takahashi E, Kawamura K (2014) Determination of Hydrogen Atoms Position in Enstatite by IR Spectra. Journal of Computer Chemistry, Japan 13, 169-170. (in Japanese).
Wang Q, Bagdassarov N, Xia Q, Zhu B (2014) Water contents and electrical conductivity of peridotite xenoliths from the North China Craton: Implications for water distribution in the upper mantle. Lithos 189, 105-126.
Warren JM, Hauri EH (2014). Pyroxenes as tracers of mantle water variations. Journal of Geophysical Research: Solid Earth 119, 1851–1881.

2015-2016

Bizimis M, Peslier AH (2015) Water in Hawaiian garnet pyroxenites: Implications for water heterogeneity in the mantle. Chemical Geology 297, 61-75.
Chen H, Xia Q, Ingrin J (2015) Water content of the Xiaogulihe ultrapotassic volcanic rocks, NE China: implications for the source of the potassium-rich component. Science Gulletin 60, 1468-1470.
Chen H, Xia Q, Ingrin J, Jia Z, Feng M (2015) Changing recycled oceanic components in the mantle source of the Shuangliao Cenozoic basalts, NE China: New constraints from water content. Tectonophysics 650, 113-123.
Hesse KR, Gose J, Stalder R, Schmadicke E (2015) Water in orthopyroxene from abyssal spinel peridotites of the East Pacific Rise (ODP Leg 147: Hess Deep). Lithos 232, 23-34.
Li P, Xia Q, Deloule E, Chen H, Gu X, Feng M (2015) Temporal variation of H<sub>2</sub>O content in the lithospheric mantle beneath the eastern North China Craton: Implications for the destruction of cratons. Gondwana Research 28, 276-287.
Liu J, Xia Q, Deloule E, Chen H, Feng M (2015) Recycled oceanic crust and marine sediment in the source of alkali basalts in Shandong, eastern China: Evidence from magma water content and oxygen isotopes.Journal of Geophysical Research: Solid Earth 120, 8281-8303.
Liu J, Xia Q, Deloule E, Ingrin J, Chen H, Feng M (2015) Water Content and Oxygen Isotopic Composition of Alkali Basalts from the Taihang Mountains, China: Recycled Oceanic Components in the Mantle Source. Journal of Petrology 56, 681-702.
Stalder, R; Karimova, A; Konzett, J (2015): OH-defects in multiple-doped orthoenstatite at 4–8 GPa: filling the gap between pure and natural systems.
In: Contributions to Mineralogy and Petrology 169, Art. Nr. 38.
Weis FA, Skogby H, Troll VR, Deegan FM, Darehn B (2015) Magmatic water contents determined through clinopyroxene: examples from the Western Canary Islands, Spain. Geochemical GeophysicalGeosystetms 16, 2127–2146.
Yang Y, Xia Q, Zhang P (2015) Evolutions of OH groups in diopside and feldspars with temperature. European Journal of Mineralogy 27, 185–192.
Grutzner T, Kohn SC, BBromiley DW, Rohrbach A, Berndt J, Klemme S (2017)
The storage capacity of fluorine in olivine and pyroxene under upper mantle conditions. Geochimica et Cosmochimica Acta 208, 160-170.
Hao Y, Xia Q, Jia Z, Zhao Q, Li P, Feng M, Liu S (2016) Regional heterogeneity in the water content of the Cenozoic lithospheric mantle of Eastern China. Journal of Geophysical Research: Solid Earth 121, 517-537.
Weis FA, Stalder R, Skogby H (2016) Experimental hydration of natural volcanic clinopyroxene phenocrysts under hydrothermal pressures (0.5–3 kbar). American Mineralologist 101, 2233–2247.
Xia Q, Bi Y, Li P, Tian W, Wei X, Chen H (2016) High water content in primitive continental flood basalts. Scientific Reports 5, 25416.

2017-2019

Stalder R, Potrafke A,; Billström K, Skogby H, Meinhold G, Gögele C, Berberich T (2017): OH-defects in quartz as monitor for igneous, metamorphic and sedimentary processes. American Mineralogist 102/9, 1832-1842.
Tian Z, Xia Q, Ingrin J, Hao Y, Christophe D (2017) Water concentration profiles in natural mantle orthopyroxenes: A geochronometer for long annealing of xenoliths within magma. Geology 45, 87-90.
Weis FA, Ros L, Reichart P, Skogby H, Kristiansson P, Dollinger G (2018) Hydrogen concentration analysis in clinopyroxene using proton–proton scattering analysis. Physics and Chemistry of Minerals 45, 669-678.
Babushkina MS, Ugolkov VL, Marin YB, Nikitina LP, Goncharov AG (2018) Hydrogen and Carbon Groups in the Structures of Rock-Forming Minerals of Rocks of the Lithospheric Mantle: FTIR and STA plus QMS Data. Docklady Earth Sciences 479, 456-459.
Frigo C, Stalder R, Hauzenberger C (2016): OH defects in quartz in granitic systems doped with spodumene, tourmaline and/or apatite: experimental investigations at 5–20 kbar. Physics And Chemistry Of Minerals 43, 717,729.
Gori C, Tribaudino M, Mezzadri F, Skogby H, Hålenius, U (2018) Co2+-doped diopside: crystal structure and optical properties. Physics and Chemistry of Minerals 45, 443-461.
Hao YT, Li P, Coltorti M, Xia QK (2018) Variations in the H₂O Content and H₂O/Ce Ratio of Mantle Pyroxenites: Implications for Enriched Components in the Mantle.Journal of Journal of Geophysical Research: Solid Earth, 123, 5628–5643.
Ivanov AV, Mukasa SB, Kamenetsky VS, Ackerson M, Demonterova EI, Pokrovsky BG, Vladykin NV, Kolesnichenko Mv, Litasov KD, Zedgenizov DA (2018) Volatile concentrations in olivine-hosted melt inclusions from meimechite and melanephelinite lavas of the Siberian Traps Large Igneous Province: Evidence for flux-related high-Ti, high-Mg magmatism. Chemical Geology 483, 442-462.
Li P, Scott JM, Liu J, Xia QK (2018) Lateral H₂O variation in the Zealandia lithospheric mantle controls orogen width. Earth and Planetary Science Letters 502, 200-209.
Marshall EW, Lassiter JC, Barnes JD (2018) On the (mis)behavior of water in the mantle: Controls on nominally anhydrous mineral water content in mantle peridotites. Earth and Planetary Science Letters 499, 219-229.
Qiu Y, Jiang H, Kovacs I, Xia QK, Yang X (2018) Quantitative analysis of H-species in anisotropic minerals by unpolarized infrared spectroscopy: An experimental evaluation. American Mineralogist 103, 1761-1769.
Schmädicke, Gose J, Stalder R (2018) Water in Abyssal Peridotite: Why Are Melt-Depleted Rocks so Water Rich? Geochemistry Geophysics Geosystems 13, 1824-1843.
Weis FA, Lazor P, Skogby H (2018) Hydrogen analysis in nominally anhydrous minerals by transmission
Raman spectroscopy. Physics and Chemistry of Minerals 45:, 597–607.
Weis FA, Ros L, Reichart P, Skogby H, Kristiansson P, Dollinger G (2018) Hydrogen concentration analysis in clinopyroxene using proton–proton scattering analysis. Physics and Chemistry of Minerals 45, 669–678.
Weis F, Stalder R, Skogby H (2016) Experimental hydration of natural volcanic clinopyroxene phenocrysts under hydrothermal pressures (0.5-3 kbar). American Mineralogist 101, 2233-2247
Demouchy S, Tommasi A, Ionov D, Higgie K, Carlson RW (2019) Microstructures, Water Contents, and Seismic Properties of the Mantle Lithosphere Beneath the Northern Limit of the Hangay Dome, Mongolia. Geochemistry, Geophysics, Geosystems, 20, 183–207.
Tollan P, Hermann J (2019) Arc magmas oxidized by water dissociation and hydrogen incorporation in orthopyroxene. Nature Geoscience 12, 667-671.
Yang Y, Ingrin J, Xia QK, Liu WD (2019) Nature of hydrogen defects in clinopyroxenes from room temperature up to 1000°C: Implication for the preservation of hydrogen in the upper mantle and impact on electricalconductivity. American Mineralogist 104, 79–93.
Reconciling the discrepancy between the dehydration rates in mantle olivine and
pyroxene during xenolith emplacement
Xu Y, Tang W, Hui H, Rudnick RL, Shang S, Zhang Z (2019) Reconciling the discrepancy between the dehydration rates in mantle olivine and pyroxene during xenolith emplacement - Geochimica et Cosmochimica Acta 267, 179-195.
Yi M, Wang Q, Yang J (2019) Fabrics and water contents of peridotites in the Neotethyan Luobusa ophiolite, southern Tibet: implications for mantle recycling in supra-subduction zones. Journal of the Geological Society 176, 975-991.

2020-2025

Balan E, Paulatto L, Liu J, Ingrin J (2020) Low-temperature infrared spectrum and atomic-scale structure of hydrous defects in diopside. European Journal of Mineralogy 32, 505-520.
Liu H, Yang X (2020) Solubility of hydroxyl groups in pyroxenes: Effect of oxygen fugacity at 0.2-3 GPa and 800-1200 ºC. Geochimica et Cosmochimica Acta 286, 355-379.
Jin TL, Wang Q, Shatsky V, Liao Y (2021) Water Content and Deformation of the Lower Crust beneath the Siberian Craton: Evidence from Granulite Xenoliths. Journal of Geology 129, 475-498.
Yang Y, Ingrin J, Liu W, Huang W, Gu X, Xia Q (2021) Behavior and origin of hydrogen defects in natural orthopyroxene during high-temperature processes. American Mineralogist 105, 1768-1779.
Gose J, Schmadicke E (2022) H₂O in omphacite of quartz and coesite eclogite from Erzgebirge and Fichtelgebirge, Germany. Journal of metamorphic Geology 40, 665-686.
Nformidah-Ndah SS, Tollan PME, Hermann J, Chouankoue JP (2022) Depletion and refertilisation of the lithospheric mantle below the Kapsiki plateau (Northern Cameroon Volcanic Line) deduced from trace element and H₂O systematics in mantle xenoliths. Journal of African Earth Sciences 189, 104483
Balan E, Kingrin J (2024) Theoretical infrared signature of OH defects in Fe³⁺, Cr³⁺ and Al³⁺-doped enstatite. Physics and Chemistry of Minerals 51, 26. https://doi.org/10.1007/s00269-024-01289-2
Demouchy S, Varou F, Ishikawa A, Gardés E, Tommasi A (2024) Microstructures, hydrogen concentrations, and seismic properties of a tectonically exhumed sliver of oceanic mantle lithosphere, Moa Island, Timor-Tanimbar outer-arc, eastern Indonesia. Tectonophysics 887, 230443. https://doi.org/10.1016/j.tecto.2024.230443
Kahn S, Liptai N, Kovács IJ, Fedortchouk Y, Tóth TM (2024) Heterogeneous water distribution in between peridotite xenoliths from Kaapvaal Craton kimberlites: Constraints on diamond barren nature ofkimberlites. Gondwana Research 147, 331-348.
Li ZY, Wang YF, Zhang JF (2024) Hydrogen loss from pyroxene within granulite xenoliths at Damaping, North China craton. Journal of Asian Earth Sciences 276, 106331.
Zhu CY, Chen H, Hao YT, Xia Q (2024) The Effects of Partial Melting and Metasomatism on Peridotite Water Contents: Insights from Shuangliao Volcano Group, Northeast China. Journal of Petrology 65, egae003. https://doi.org/10.1093/petrology/egae003
Geiger H, Weis F, Troll VR, Deegan FM, Skogby H, Carracedo JC (2025). Explosive ocean island volcanism explained by high magmatic water content determined through nominally anhydrous minerals. Geochemistry, Geophysics, Geosystems, 26, e2024GC012013. https://doi.org/10.1029/2024GC012013
Jiang Y, Yu J, Ouyang Y, Zhang L, Li X, Zhang Z, Li Y (2025) Crystal Chemistry, High-Pressure Behavior, Water Content, and Thermal Stability of Natural Spodumene. Minerals 2025, 15, 307. https://doi.org/10.3390/min15030307
Schmädicke E, Gose J, Stachel T (2025) Water in Eclogite and Pyroxenite Xenoliths From the Bottom 100 km of the Slave Craton (Canada) Mantle Root. Geochemistry, Geophysics, Geosystems. 26, e2024GC011922.