H in Stishovite
Updated 5-Nov-2025 by GR Rossman
1990s
- Pawley AR, McMillan PF, Holloway JR (1993) Hydrogen
in Stishovite, with Implications for Mantle Water Content. Science
261, 1024-1026.
- Smyth
J, Swope R, Pawley A (1995) H in rutile-type compounds: II. Crystal
chemistry of Al substitution in H-bearing stishovite. American
Mineralogist 80, 454–456.
2000s
- Mosenfelder JL (2000) Pressure dependence of hydroxyl solubility in coesite. Physics and Chemistry of Minerals 27, 610-617.
- Chung Ji, Kagi H (2002) High concentration of
water in stishovite in the MORB system. Geophysical Research Letters
29, DOI 10.1029/2002GL015579
- Panero
WR, Benedetti LR, Jeanloz R (2003) Transport of water into lower
mantle: role of stishovite. J Geophys Res 108 (B1). DOI
10.1029/2002JB002053
- Gibbs G, Cox D, Ross
N (2004) A modeling of the structure and favourable H-docking sites and
defects for the high-pressure silica polymorph stishovite. Physics and Chemistry of
Minerals 31, 232–239.
- Panero
WR, Stixrude LP (2004) Hydrogen incorporation in stishovite at high
pressure and symmetric bonding in delta-AlOOH. Earth Planet Science
Letters 221, 421–431.
- Bromiley GD, Bromiley FA, Bromiley DW (2006) On the
mechanisms for H and Al incorporstion in stishovite. Physics
and Chemistry of
Minerals 33, 613-621.
- Litasov
K, Ohtani E, Kagi H, Lakshtanov D, Bass Jay (2006) Hydrogen solubility
in Al-rich stishovite and water transport to the lower mantle.
Geochimica et Cosmochimica Acta. 70. A362. 10.1016/j.gca.2006.06.732.
- Lakshtanov DL, Litasov KD, Sinogeikin SV, Hellwig H (2007) Effect of Al3+ and H+ on the elastic properties of stishovite. American Mineralogist 92, 1026-1030;
- Litasov, K. D., Kagi, H., Shatskiy, A.,
Ohtani, E., Lakshtanov, D. L., Bass, J. D., & Ito, E. (2007).
High hydrogen solubility in Al‐rich stishovite and water transport in the lower mantle. Earth and Planetary
Science Letters, 262, 620–634.
- Thomas SM, Koch-Mueller M, Reichart P,
Rhede CX, Thomas R, Wirth R, Matsyuk S (2009) IR calibrations for water
determination in
olivine, r-GeO2, and SiO2
polymorphs. Physics and Chemistry of Minerals 36, 489-509
2010s
- Spektor K, Nylen J, Stoyanov E, Navrotsky
A, Hervig RL,
Leinenweber K, et al. (2011). Ultrahydrous stishovite from
high‐pressure hydrothermal treatment of SiO2. Proceedings of the
National Academy of
Sciences, 108, 20,918–20,922.
- Nisr
C, Shim SH, Leinenweber K, Chizmeshya A (2017) Raman spectroscopy of
water-rich stishovite and dense high-pressure silica up to 55 GPa.
American Mineralogist 102, 2280-2189.
- Frigo C, Stalder R, Ludwig
T (2019) OH defects in coesite and stishovite during ultrahigh-pressure
metamorphism of continental crust. Physics and Chemistry of
Minerals 46, 77–89
- Li
J, Lin Y, Meier T, Liu Z, Yng W, Mao H-K, Zhu S, Hu Q (2023)
Silica-water superstructure and one-dimensional superionic conduit in
Earth’s mantle. Science Advances 9, eadh3784.
doi/10.1126/sciadv.adh3784
2020s
- Ishii T, Criniti G, Purevjav N, Katsura T, Ohtani E (2024)
Hydrogen partitioning between stishovite and hydrous phase δ:
implications for water cycle and distribution in the lower mantle.
Progress in Earth and Planetary Science 11:10 https://doi.org/10.1186/s40645-024-00615-0
- Zhang L, Smyth JR, Xu C (2025) Crystal chemistry and
high-temperature behavior of Al-bearing stishovite and Al-rich phase D:
Implications for water storage in the deep mantle. American
Mineralogist 110, 1854-1864. https://doi.org/10.2138/am-2024-9665