| Harvey J. Schugar Department of Chemistry Rutgers University New Brunswick, New Jersey George R. Rossman, Harry B. Gray Arthur Amos Noyes Laboratory of Chemical Physics California Institute of Technology Pasadena, CA 91125 |
Abstract
Here we report the isolation and
characterization of [Fe(pic)2OH]2, a
ferric iron picolinate dimer whch apparently is the first example of a
crystalline iron(III) dimer which utilized dihydroxo bridging in its
coordination structure. Its magnetic susceptibility dat in the range
16-229 K is consistent with a hydroxo-bridged dimer.
The magnetic moment vs
temperature of the ferric picolinate hydroxy dimer
last updated: 25-Jul-2023