| Harvey J. Schugar Department of Chemistry Rutgers University New Brunswick, New Jersey George R. Rossman, Jack Thibeault, Harry B. Gray Arthur Amos Noyes Laboratory of Chemical Physics California Institute of Technology Pasadena, CA 91125 |
Abstract
The spectrum of th ethylenediammonium salt of the dimeric Fe(III) comples ion [(HEDTAFe)2O]2- was examined. The ultravloIet absorption spectrum
of this isolated metal complex containing the bridging unit Fe(lII)···O···Fe(III) slows several bands due to the simultaneol!s
electronic excitation of the two Fe(III) centers. The band positiors are in excelient agreement with calculated
sums of one-center d-d transitions.
The magnetic moment vs
temperature of the ferric picolinate hydroxy dimer
last updated: 25-Jul-2023